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2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate
In the title compound, C(16)H(11)NO(2)·C(5)H(9)NO, the dihedral angles between the maleimide and phenyl rings are 34.7 (2) and 64.8 (2)°. In the crystal, the 2,3-diphenylmaleimide and 1-methylpyrrolidin-2-one molecules form centrosymmetrical dimers via pairs of strong N—H⋯O hydrogen bonds and...
Autores principales: | , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998429/ https://www.ncbi.nlm.nih.gov/pubmed/24764976 http://dx.doi.org/10.1107/S1600536814002372 |
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author | Bulatov, Evgeny Boyarskaya, Dina Chulkova, Tatiana Haukka, Matti |
author_facet | Bulatov, Evgeny Boyarskaya, Dina Chulkova, Tatiana Haukka, Matti |
author_sort | Bulatov, Evgeny |
collection | PubMed |
description | In the title compound, C(16)H(11)NO(2)·C(5)H(9)NO, the dihedral angles between the maleimide and phenyl rings are 34.7 (2) and 64.8 (2)°. In the crystal, the 2,3-diphenylmaleimide and 1-methylpyrrolidin-2-one molecules form centrosymmetrical dimers via pairs of strong N—H⋯O hydrogen bonds and π–π stacking interactions between the two neighboring maleimide rings [centroid–centroid distance = 3.495 (2) Å]. The dimers are further linked by weak C—H⋯O and C—H⋯π hydrogen bonds into a three-dimensional framework. |
format | Online Article Text |
id | pubmed-3998429 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984292014-04-24 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate Bulatov, Evgeny Boyarskaya, Dina Chulkova, Tatiana Haukka, Matti Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(11)NO(2)·C(5)H(9)NO, the dihedral angles between the maleimide and phenyl rings are 34.7 (2) and 64.8 (2)°. In the crystal, the 2,3-diphenylmaleimide and 1-methylpyrrolidin-2-one molecules form centrosymmetrical dimers via pairs of strong N—H⋯O hydrogen bonds and π–π stacking interactions between the two neighboring maleimide rings [centroid–centroid distance = 3.495 (2) Å]. The dimers are further linked by weak C—H⋯O and C—H⋯π hydrogen bonds into a three-dimensional framework. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998429/ /pubmed/24764976 http://dx.doi.org/10.1107/S1600536814002372 Text en © Bulatov et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Bulatov, Evgeny Boyarskaya, Dina Chulkova, Tatiana Haukka, Matti 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
title | 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
title_full | 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
title_fullStr | 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
title_full_unstemmed | 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
title_short | 2,3-Diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
title_sort | 2,3-diphenylmaleimide 1-methylpyrrolidin-2-one monosolvate |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998429/ https://www.ncbi.nlm.nih.gov/pubmed/24764976 http://dx.doi.org/10.1107/S1600536814002372 |
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