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Dichloridodimethylbis(thiourea-κS)tin(IV)
The title compound, [Sn(CH(3))(2)Cl(2)(CH(4)N(2)S)(2)], crystallizes with two half-molecules in the asymmetric unit. Both molecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octahedral coordination environments defin...
| Autores principales: | , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998430/ https://www.ncbi.nlm.nih.gov/pubmed/24764948 http://dx.doi.org/10.1107/S1600536814002025 |
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| author | Sow, Yaya Diop, Libasse Fernandes, Manuel A. Stoeckli-Evans, Helen |
| author_facet | Sow, Yaya Diop, Libasse Fernandes, Manuel A. Stoeckli-Evans, Helen |
| author_sort | Sow, Yaya |
| collection | PubMed |
| description | The title compound, [Sn(CH(3))(2)Cl(2)(CH(4)N(2)S)(2)], crystallizes with two half-molecules in the asymmetric unit. Both molecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octahedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thiourea S atoms. In the crystal, molecules are linked via N—H⋯Cl and N—H⋯S hydrogen bonds, forming a three-dimensional structure. |
| format | Online Article Text |
| id | pubmed-3998430 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39984302014-04-24 Dichloridodimethylbis(thiourea-κS)tin(IV) Sow, Yaya Diop, Libasse Fernandes, Manuel A. Stoeckli-Evans, Helen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Sn(CH(3))(2)Cl(2)(CH(4)N(2)S)(2)], crystallizes with two half-molecules in the asymmetric unit. Both molecules are completed by inversion symmetry with the two Sn(IV) atoms located on inversion centers. The metal atoms have distorted octahedral coordination environments defined by two Cl atoms, two C atoms of methyl groups and two thiourea S atoms. In the crystal, molecules are linked via N—H⋯Cl and N—H⋯S hydrogen bonds, forming a three-dimensional structure. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998430/ /pubmed/24764948 http://dx.doi.org/10.1107/S1600536814002025 Text en © Sow et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sow, Yaya Diop, Libasse Fernandes, Manuel A. Stoeckli-Evans, Helen Dichloridodimethylbis(thiourea-κS)tin(IV) |
| title | Dichloridodimethylbis(thiourea-κS)tin(IV) |
| title_full | Dichloridodimethylbis(thiourea-κS)tin(IV) |
| title_fullStr | Dichloridodimethylbis(thiourea-κS)tin(IV) |
| title_full_unstemmed | Dichloridodimethylbis(thiourea-κS)tin(IV) |
| title_short | Dichloridodimethylbis(thiourea-κS)tin(IV) |
| title_sort | dichloridodimethylbis(thiourea-κs)tin(iv) |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998430/ https://www.ncbi.nlm.nih.gov/pubmed/24764948 http://dx.doi.org/10.1107/S1600536814002025 |
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