4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone

In the title compound, C(15)H(15)N(3)O(2)S, the central C—N—N—C unit has an anti conformation [torsion angle = −170.17 (15)°]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2 (1)°], whereas the substituted ring is rotated out of this plane by only 18.86 (17)°. I...

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Autores principales: de Oliveira, Adriano Bof, Feitosa, Bárbara Regina Santos, Näther, Christian, Jess, Inke
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998432/
https://www.ncbi.nlm.nih.gov/pubmed/24764990
http://dx.doi.org/10.1107/S1600536814002773
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author de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_facet de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
author_sort de Oliveira, Adriano Bof
collection PubMed
description In the title compound, C(15)H(15)N(3)O(2)S, the central C—N—N—C unit has an anti conformation [torsion angle = −170.17 (15)°]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2 (1)°], whereas the substituted ring is rotated out of this plane by only 18.86 (17)°. In the crystal, mol­ecules are linked by pairs of N—H⋯S hydrogen bonds into inversion dimers that are further connected via N—H⋯O and O—H⋯S hydrogen bonds into a three-dimensional network.
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spelling pubmed-39984322014-04-24 4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone de Oliveira, Adriano Bof Feitosa, Bárbara Regina Santos Näther, Christian Jess, Inke Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(15)N(3)O(2)S, the central C—N—N—C unit has an anti conformation [torsion angle = −170.17 (15)°]. The phenyl substituent is oriented perpendicular to this unit [dihedral angle of 89.2 (1)°], whereas the substituted ring is rotated out of this plane by only 18.86 (17)°. In the crystal, mol­ecules are linked by pairs of N—H⋯S hydrogen bonds into inversion dimers that are further connected via N—H⋯O and O—H⋯S hydrogen bonds into a three-dimensional network. International Union of Crystallography 2014-02-12 /pmc/articles/PMC3998432/ /pubmed/24764990 http://dx.doi.org/10.1107/S1600536814002773 Text en © Oliveira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
de Oliveira, Adriano Bof
Feitosa, Bárbara Regina Santos
Näther, Christian
Jess, Inke
4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
title 4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
title_full 4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
title_fullStr 4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
title_full_unstemmed 4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
title_short 4-Hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
title_sort 4-hy­droxy-3-meth­oxy­benzaldehyde 4-phenyl­thio­semicarbazone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998432/
https://www.ncbi.nlm.nih.gov/pubmed/24764990
http://dx.doi.org/10.1107/S1600536814002773
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