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catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]

In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-bis­(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octa­hedron...

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Detalles Bibliográficos
Autores principales: Tanaka, Seiya, Himegi, Akiko, Ohishi, Tomomi, Fuyuhiro, Akira, Kawata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998436/
https://www.ncbi.nlm.nih.gov/pubmed/24764952
http://dx.doi.org/10.1107/S1600536814002396
Descripción
Sumario:In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-bis­(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octa­hedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol mol­ecules. The chloranilate ion serves as a bridging ligand between the Mn(II) ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O—H⋯O hydrogen bonds between the apically coordinating ethanol mol­ecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane.