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catena-Poly[[bis(ethanol-κO)manganese(II)]-μ-2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olato)-κ(4) O (1),O (6):O (3),O (4)]
In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octahedron...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998436/ https://www.ncbi.nlm.nih.gov/pubmed/24764952 http://dx.doi.org/10.1107/S1600536814002396 |
Sumario: | In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-dichloro-3,6-dioxocyclohexa-1,4-diene-1,4-bis(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octahedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol molecules. The chloranilate ion serves as a bridging ligand between the Mn(II) ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O—H⋯O hydrogen bonds between the apically coordinating ethanol molecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane. |
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