catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]

In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-bis­(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octa­hedron...

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Detalles Bibliográficos
Autores principales: Tanaka, Seiya, Himegi, Akiko, Ohishi, Tomomi, Fuyuhiro, Akira, Kawata, Satoshi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998436/
https://www.ncbi.nlm.nih.gov/pubmed/24764952
http://dx.doi.org/10.1107/S1600536814002396
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author Tanaka, Seiya
Himegi, Akiko
Ohishi, Tomomi
Fuyuhiro, Akira
Kawata, Satoshi
author_facet Tanaka, Seiya
Himegi, Akiko
Ohishi, Tomomi
Fuyuhiro, Akira
Kawata, Satoshi
author_sort Tanaka, Seiya
collection PubMed
description In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-bis­(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octa­hedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol mol­ecules. The chloranilate ion serves as a bridging ligand between the Mn(II) ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O—H⋯O hydrogen bonds between the apically coordinating ethanol mol­ecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane.
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spelling pubmed-39984362014-04-24 catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)] Tanaka, Seiya Himegi, Akiko Ohishi, Tomomi Fuyuhiro, Akira Kawata, Satoshi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title coordination polymer, [Mn(C(6)Cl(2)O(4))(C(2)H(5)OH)(2)](n), the Mn(II) atom and the chloranilate [systematic name: 2,5-di­chloro-3,6-dioxo­cyclo­hexa-1,4-diene-1,4-bis­(olate)] ion lie on crystallographic inversion centers. The geometry around the Mn(II) atom is a distorted octa­hedron involving four O atoms of two chloranilate ions and two O atoms from two ethanol mol­ecules. The chloranilate ion serves as a bridging ligand between the Mn(II) ions, leading to an infinite linear chain along the b-axis direction. The chains are linked by O—H⋯O hydrogen bonds between the apically coordinating ethanol mol­ecule and the chloranilate ion, affording a two-dimensional layer expanding parallel to the ab plane. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998436/ /pubmed/24764952 http://dx.doi.org/10.1107/S1600536814002396 Text en © Tanaka et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Tanaka, Seiya
Himegi, Akiko
Ohishi, Tomomi
Fuyuhiro, Akira
Kawata, Satoshi
catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]
title catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]
title_full catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]
title_fullStr catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]
title_full_unstemmed catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]
title_short catena-Poly[[bis­(ethanol-κO)mangan­ese(II)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) O (1),O (6):O (3),O (4)]
title_sort catena-poly[[bis­(ethanol-κo)mangan­ese(ii)]-μ-2,5-di­chloro-3,6-di­oxo­cyclo­hexa-1,4-diene-1,4-bis­(olato)-κ(4) o (1),o (6):o (3),o (4)]
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998436/
https://www.ncbi.nlm.nih.gov/pubmed/24764952
http://dx.doi.org/10.1107/S1600536814002396
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