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Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate

In the title compound, C(17)H(17)N(3)O(3)S, the thia­zole ring is nearly planar [maximum deviation = 0.015 (1) Å for the ring N atom] and the cyclo­pentane ring has a twist conformation. The mol­ecular conformation is stabilized by a hypervalent inter­action between the S atom and the ester group ca...

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Autores principales: Mague, Joel T., Akkurt, Mehmet, Mohamed, Shaaban K., Hassan, Alaa A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998438/
https://www.ncbi.nlm.nih.gov/pubmed/24765050
http://dx.doi.org/10.1107/S1600536814004048
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author Mague, Joel T.
Akkurt, Mehmet
Mohamed, Shaaban K.
Hassan, Alaa A.
Albayati, Mustafa R.
author_facet Mague, Joel T.
Akkurt, Mehmet
Mohamed, Shaaban K.
Hassan, Alaa A.
Albayati, Mustafa R.
author_sort Mague, Joel T.
collection PubMed
description In the title compound, C(17)H(17)N(3)O(3)S, the thia­zole ring is nearly planar [maximum deviation = 0.015 (1) Å for the ring N atom] and the cyclo­pentane ring has a twist conformation. The mol­ecular conformation is stabilized by a hypervalent inter­action between the S atom and the ester group carbonyl O atom, with an S⋯O distance of 2.7931 (10) Å. In the crystal, C—H⋯O inter­actions generate chains of mol­ecules propagating along [110] and π–π stacking inter­actions [centroid–centroid distance = 3.4677 (7) Å] between the thia­zole rings organize these chains into (001) layers.
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spelling pubmed-39984382014-04-24 Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate Mague, Joel T. Akkurt, Mehmet Mohamed, Shaaban K. Hassan, Alaa A. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(17)N(3)O(3)S, the thia­zole ring is nearly planar [maximum deviation = 0.015 (1) Å for the ring N atom] and the cyclo­pentane ring has a twist conformation. The mol­ecular conformation is stabilized by a hypervalent inter­action between the S atom and the ester group carbonyl O atom, with an S⋯O distance of 2.7931 (10) Å. In the crystal, C—H⋯O inter­actions generate chains of mol­ecules propagating along [110] and π–π stacking inter­actions [centroid–centroid distance = 3.4677 (7) Å] between the thia­zole rings organize these chains into (001) layers. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998438/ /pubmed/24765050 http://dx.doi.org/10.1107/S1600536814004048 Text en © Mague et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Mague, Joel T.
Akkurt, Mehmet
Mohamed, Shaaban K.
Hassan, Alaa A.
Albayati, Mustafa R.
Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
title Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
title_full Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
title_fullStr Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
title_full_unstemmed Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
title_short Methyl (2Z)-2-{(2Z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
title_sort methyl (2z)-2-{(2z)-3-[(cyclo­pentyl­idene)amino]-4-oxo-2-phenyl­imino-1,3-thia­zol­idin-5-yl­idene}acetate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998438/
https://www.ncbi.nlm.nih.gov/pubmed/24765050
http://dx.doi.org/10.1107/S1600536814004048
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