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Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione

The title compound, C(19)H(17)PS(2), results from the direct deprotonation of di­phenyl­methyl­phosphine sulfide and subsequent reaction with diphenyl di­sulfide. The C—P and C—S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P—C—S linkage are comparable to those found i...

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Detalles Bibliográficos
Autor principal: Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998441/
https://www.ncbi.nlm.nih.gov/pubmed/24765055
http://dx.doi.org/10.1107/S1600536814004292
Descripción
Sumario:The title compound, C(19)H(17)PS(2), results from the direct deprotonation of di­phenyl­methyl­phosphine sulfide and subsequent reaction with diphenyl di­sulfide. The C—P and C—S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P—C—S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the di­phenyl­methyl moiety is 69.46 (7)°. No distinct inter­molecular inter­actions are present in the crystal structure.