Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione

The title compound, C(19)H(17)PS(2), results from the direct deprotonation of di­phenyl­methyl­phosphine sulfide and subsequent reaction with diphenyl di­sulfide. The C—P and C—S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P—C—S linkage are comparable to those found i...

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Autor principal: Gessner, Viktoria H.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998441/
https://www.ncbi.nlm.nih.gov/pubmed/24765055
http://dx.doi.org/10.1107/S1600536814004292
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author Gessner, Viktoria H.
author_facet Gessner, Viktoria H.
author_sort Gessner, Viktoria H.
collection PubMed
description The title compound, C(19)H(17)PS(2), results from the direct deprotonation of di­phenyl­methyl­phosphine sulfide and subsequent reaction with diphenyl di­sulfide. The C—P and C—S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P—C—S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the di­phenyl­methyl moiety is 69.46 (7)°. No distinct inter­molecular inter­actions are present in the crystal structure.
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spelling pubmed-39984412014-04-24 Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione Gessner, Viktoria H. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(19)H(17)PS(2), results from the direct deprotonation of di­phenyl­methyl­phosphine sulfide and subsequent reaction with diphenyl di­sulfide. The C—P and C—S bond lengths of 1.8242 (18) and 1.8009 (18) Å, respectively, of the central P—C—S linkage are comparable to those found in the sulfonyl analogue, but are considerably longer than those reported for the dimetallated sulfonyl compound. The dihedral angle between the benzene rings of the di­phenyl­methyl moiety is 69.46 (7)°. No distinct inter­molecular inter­actions are present in the crystal structure. International Union of Crystallography 2014-02-28 /pmc/articles/PMC3998441/ /pubmed/24765055 http://dx.doi.org/10.1107/S1600536814004292 Text en © Viktoria H. Gessner 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Gessner, Viktoria H.
Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
title Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
title_full Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
title_fullStr Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
title_full_unstemmed Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
title_short Diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
title_sort diphen­yl[(phenyl­sulfan­yl)meth­yl]-λ(5)-phosphane­thione
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998441/
https://www.ncbi.nlm.nih.gov/pubmed/24765055
http://dx.doi.org/10.1107/S1600536814004292
work_keys_str_mv AT gessnerviktoriah diphenylphenylsulfanylmethyll5phosphanethione

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