1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one

The β-lactam (azetidin-2-one) ring of the title compound, C(28)H(27)N(3)O(5), is nearly planar [maximum deviation = 0.010 (1) Å] and makes dihedral angles of 75.77 (5), 52.78 (9) and 88.72 (5)°, respectively, with the benzene ring, the least-squares plane formed by the four C atoms of the morpholine...

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Detalles Bibliográficos
Autores principales: Çelik, Ísmail, Akkurt, Mehmet, Jarrahpour, Aliasghar, Heiran, Roghayeh, Özdemir, Namık
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998443/
https://www.ncbi.nlm.nih.gov/pubmed/24765052
http://dx.doi.org/10.1107/S160053681400419X
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author Çelik, Ísmail
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghayeh
Özdemir, Namık
author_facet Çelik, Ísmail
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghayeh
Özdemir, Namık
author_sort Çelik, Ísmail
collection PubMed
description The β-lactam (azetidin-2-one) ring of the title compound, C(28)H(27)N(3)O(5), is nearly planar [maximum deviation = 0.010 (1) Å] and makes dihedral angles of 75.77 (5), 52.78 (9) and 88.72 (5)°, respectively, with the benzene ring, the least-squares plane formed by the four C atoms of the morpholine ring, which adopts a chair conformation, and the xanthene ring system. In the crystal, C—H⋯O hydrogen-bond contacts connect neighbouring mol­ecules into infinite zigzag chains running parallel to the b axis.
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spelling pubmed-39984432014-04-24 1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one Çelik, Ísmail Akkurt, Mehmet Jarrahpour, Aliasghar Heiran, Roghayeh Özdemir, Namık Acta Crystallogr Sect E Struct Rep Online Organic Papers The β-lactam (azetidin-2-one) ring of the title compound, C(28)H(27)N(3)O(5), is nearly planar [maximum deviation = 0.010 (1) Å] and makes dihedral angles of 75.77 (5), 52.78 (9) and 88.72 (5)°, respectively, with the benzene ring, the least-squares plane formed by the four C atoms of the morpholine ring, which adopts a chair conformation, and the xanthene ring system. In the crystal, C—H⋯O hydrogen-bond contacts connect neighbouring mol­ecules into infinite zigzag chains running parallel to the b axis. International Union of Crystallography 2014-02-28 /pmc/articles/PMC3998443/ /pubmed/24765052 http://dx.doi.org/10.1107/S160053681400419X Text en © Çelik et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Çelik, Ísmail
Akkurt, Mehmet
Jarrahpour, Aliasghar
Heiran, Roghayeh
Özdemir, Namık
1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
title 1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
title_full 1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
title_fullStr 1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
title_full_unstemmed 1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
title_short 1-[3-(Morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
title_sort 1-[3-(morpholin-4-yl)prop­yl]-4-(3-nitro­phen­yl)spiro­[azetidine-3,9′-xanthen]-2-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998443/
https://www.ncbi.nlm.nih.gov/pubmed/24765052
http://dx.doi.org/10.1107/S160053681400419X
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