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Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2) O,O′]nickel(II)
In the centrosymmetric title compound, [Ni(C(7)H(6)FN(2)O(2))(2)(H(2)O)(2)], the Ni(II) cation is in a slightly distorted octahedral environment and is surrounded by four O atoms from the N—O groups of the organic ligands [Ni—O = 2.0179 (13) and 2.0283 (12) Å], and two water molecules [Ni—O = 2.09...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998445/ https://www.ncbi.nlm.nih.gov/pubmed/24764956 http://dx.doi.org/10.1107/S1600536814002876 |
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author | Kovalchukova, Olga Bostanabad, Ali Sheikh Stash, Adam Strashnova, Svetlana Zyuzin, Igor |
author_facet | Kovalchukova, Olga Bostanabad, Ali Sheikh Stash, Adam Strashnova, Svetlana Zyuzin, Igor |
author_sort | Kovalchukova, Olga |
collection | PubMed |
description | In the centrosymmetric title compound, [Ni(C(7)H(6)FN(2)O(2))(2)(H(2)O)(2)], the Ni(II) cation is in a slightly distorted octahedral environment and is surrounded by four O atoms from the N—O groups of the organic ligands [Ni—O = 2.0179 (13) and 2.0283 (12) Å], and two water molecules [Ni—O = 2.0967 (14) Å]. The N-(2-fluorobenzyl)-N-nitrosohydroxylaminate monoanions act as bidentate chelating ligands. In the crystal, the Ni cations in the columns are shifted in such a way that the coordinated water molecules are involved in the formation of hydrogen bonds with the O atoms of the organic species of neighbouring molecules. Thus, a two-dimensional network parallel to (100) is built up by hydrogen-bonded molecules. |
format | Online Article Text |
id | pubmed-3998445 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984452014-04-24 Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2) O,O′]nickel(II) Kovalchukova, Olga Bostanabad, Ali Sheikh Stash, Adam Strashnova, Svetlana Zyuzin, Igor Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the centrosymmetric title compound, [Ni(C(7)H(6)FN(2)O(2))(2)(H(2)O)(2)], the Ni(II) cation is in a slightly distorted octahedral environment and is surrounded by four O atoms from the N—O groups of the organic ligands [Ni—O = 2.0179 (13) and 2.0283 (12) Å], and two water molecules [Ni—O = 2.0967 (14) Å]. The N-(2-fluorobenzyl)-N-nitrosohydroxylaminate monoanions act as bidentate chelating ligands. In the crystal, the Ni cations in the columns are shifted in such a way that the coordinated water molecules are involved in the formation of hydrogen bonds with the O atoms of the organic species of neighbouring molecules. Thus, a two-dimensional network parallel to (100) is built up by hydrogen-bonded molecules. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998445/ /pubmed/24764956 http://dx.doi.org/10.1107/S1600536814002876 Text en © Kovalchukova et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Kovalchukova, Olga Bostanabad, Ali Sheikh Stash, Adam Strashnova, Svetlana Zyuzin, Igor Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2) O,O′]nickel(II) |
title | Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2)
O,O′]nickel(II) |
title_full | Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2)
O,O′]nickel(II) |
title_fullStr | Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2)
O,O′]nickel(II) |
title_full_unstemmed | Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2)
O,O′]nickel(II) |
title_short | Diaquabis[N-(2-fluorobenzyl)-N-nitrosohydroxylaminato-κ(2)
O,O′]nickel(II) |
title_sort | diaquabis[n-(2-fluorobenzyl)-n-nitrosohydroxylaminato-κ(2)
o,o′]nickel(ii) |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998445/ https://www.ncbi.nlm.nih.gov/pubmed/24764956 http://dx.doi.org/10.1107/S1600536814002876 |
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