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2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol
The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent molecules. In each molecule, the C=N bond is in an E conformation. The most significant difference between the two molecules is seen for the dihedral angles between the methoxy-substituted benzene ri...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998446/ https://www.ncbi.nlm.nih.gov/pubmed/24765015 http://dx.doi.org/10.1107/S1600536814003195 |
Sumario: | The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent molecules. In each molecule, the C=N bond is in an E conformation. The most significant difference between the two molecules is seen for the dihedral angles between the methoxy-substituted benzene ring and the two phenyl rings, which are 85.5 (1) and 82.3 (1)° in the first molecule, and 49.0 (1) and 40.4 (1)° in the second. This conformational difference is reflected in the central C=N—C C torsion angle, which is 28.7 (2)° in the first molecule and −29.8 (3)° in the other. In each molecule, there is an intramolecular O—H⋯N hydrogen bond. |
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