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2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol

The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent mol­ecules. In each mol­ecule, the C=N bond is in an E conformation. The most significant difference between the two mol­ecules is seen for the dihedral angles between the meth­oxy-substituted benzene ri...

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Detalles Bibliográficos
Autores principales: Chen, Jiang, Jin, Zhe-Peng, Gao, Bing-Fei, Yu, Jian-Hua, Wu, Jie-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998446/
https://www.ncbi.nlm.nih.gov/pubmed/24765015
http://dx.doi.org/10.1107/S1600536814003195
Descripción
Sumario:The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent mol­ecules. In each mol­ecule, the C=N bond is in an E conformation. The most significant difference between the two mol­ecules is seen for the dihedral angles between the meth­oxy-substituted benzene ring and the two phenyl rings, which are 85.5 (1) and 82.3 (1)° in the first mol­ecule, and 49.0 (1) and 40.4 (1)° in the second. This conformational difference is reflected in the central C=N—C C torsion angle, which is 28.7 (2)° in the first mol­ecule and −29.8 (3)° in the other. In each mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond.