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2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol
The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent molecules. In each molecule, the C=N bond is in an E conformation. The most significant difference between the two molecules is seen for the dihedral angles between the methoxy-substituted benzene ri...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998446/ https://www.ncbi.nlm.nih.gov/pubmed/24765015 http://dx.doi.org/10.1107/S1600536814003195 |
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author | Chen, Jiang Jin, Zhe-Peng Gao, Bing-Fei Yu, Jian-Hua Wu, Jie-Ying |
author_facet | Chen, Jiang Jin, Zhe-Peng Gao, Bing-Fei Yu, Jian-Hua Wu, Jie-Ying |
author_sort | Chen, Jiang |
collection | PubMed |
description | The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent molecules. In each molecule, the C=N bond is in an E conformation. The most significant difference between the two molecules is seen for the dihedral angles between the methoxy-substituted benzene ring and the two phenyl rings, which are 85.5 (1) and 82.3 (1)° in the first molecule, and 49.0 (1) and 40.4 (1)° in the second. This conformational difference is reflected in the central C=N—C C torsion angle, which is 28.7 (2)° in the first molecule and −29.8 (3)° in the other. In each molecule, there is an intramolecular O—H⋯N hydrogen bond. |
format | Online Article Text |
id | pubmed-3998446 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984462014-04-24 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol Chen, Jiang Jin, Zhe-Peng Gao, Bing-Fei Yu, Jian-Hua Wu, Jie-Ying Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent molecules. In each molecule, the C=N bond is in an E conformation. The most significant difference between the two molecules is seen for the dihedral angles between the methoxy-substituted benzene ring and the two phenyl rings, which are 85.5 (1) and 82.3 (1)° in the first molecule, and 49.0 (1) and 40.4 (1)° in the second. This conformational difference is reflected in the central C=N—C C torsion angle, which is 28.7 (2)° in the first molecule and −29.8 (3)° in the other. In each molecule, there is an intramolecular O—H⋯N hydrogen bond. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998446/ /pubmed/24765015 http://dx.doi.org/10.1107/S1600536814003195 Text en © Chen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chen, Jiang Jin, Zhe-Peng Gao, Bing-Fei Yu, Jian-Hua Wu, Jie-Ying 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol |
title | 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol |
title_full | 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol |
title_fullStr | 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol |
title_full_unstemmed | 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol |
title_short | 2-{(E)-[4-(Diphenylamino)phenyl]iminomethyl}phenol |
title_sort | 2-{(e)-[4-(diphenylamino)phenyl]iminomethyl}phenol |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998446/ https://www.ncbi.nlm.nih.gov/pubmed/24765015 http://dx.doi.org/10.1107/S1600536814003195 |
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