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2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol

The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent mol­ecules. In each mol­ecule, the C=N bond is in an E conformation. The most significant difference between the two mol­ecules is seen for the dihedral angles between the meth­oxy-substituted benzene ri...

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Autores principales: Chen, Jiang, Jin, Zhe-Peng, Gao, Bing-Fei, Yu, Jian-Hua, Wu, Jie-Ying
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998446/
https://www.ncbi.nlm.nih.gov/pubmed/24765015
http://dx.doi.org/10.1107/S1600536814003195
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author Chen, Jiang
Jin, Zhe-Peng
Gao, Bing-Fei
Yu, Jian-Hua
Wu, Jie-Ying
author_facet Chen, Jiang
Jin, Zhe-Peng
Gao, Bing-Fei
Yu, Jian-Hua
Wu, Jie-Ying
author_sort Chen, Jiang
collection PubMed
description The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent mol­ecules. In each mol­ecule, the C=N bond is in an E conformation. The most significant difference between the two mol­ecules is seen for the dihedral angles between the meth­oxy-substituted benzene ring and the two phenyl rings, which are 85.5 (1) and 82.3 (1)° in the first mol­ecule, and 49.0 (1) and 40.4 (1)° in the second. This conformational difference is reflected in the central C=N—C C torsion angle, which is 28.7 (2)° in the first mol­ecule and −29.8 (3)° in the other. In each mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond.
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spelling pubmed-39984462014-04-24 2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol Chen, Jiang Jin, Zhe-Peng Gao, Bing-Fei Yu, Jian-Hua Wu, Jie-Ying Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title Schiff base molecule, C(25)H(20)N(2)O, contains two independent mol­ecules. In each mol­ecule, the C=N bond is in an E conformation. The most significant difference between the two mol­ecules is seen for the dihedral angles between the meth­oxy-substituted benzene ring and the two phenyl rings, which are 85.5 (1) and 82.3 (1)° in the first mol­ecule, and 49.0 (1) and 40.4 (1)° in the second. This conformational difference is reflected in the central C=N—C C torsion angle, which is 28.7 (2)° in the first mol­ecule and −29.8 (3)° in the other. In each mol­ecule, there is an intra­molecular O—H⋯N hydrogen bond. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998446/ /pubmed/24765015 http://dx.doi.org/10.1107/S1600536814003195 Text en © Chen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Jiang
Jin, Zhe-Peng
Gao, Bing-Fei
Yu, Jian-Hua
Wu, Jie-Ying
2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
title 2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
title_full 2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
title_fullStr 2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
title_full_unstemmed 2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
title_short 2-{(E)-[4-(Di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
title_sort 2-{(e)-[4-(di­phenyl­amino)­phen­yl]imino­meth­yl}phenol
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998446/
https://www.ncbi.nlm.nih.gov/pubmed/24765015
http://dx.doi.org/10.1107/S1600536814003195
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