Di­aqua­bis­(cinnamato-κ(2) O,O′)cadmium

The title complex, [Cd(C(9)H(7)O(2))(2)(H(2)O)(2)], was obtained as an unintended product of the reaction of cadmium nitrate with hexa­methyl­ene­tetra­mine and cinnamic acid. The Cd(II) ion lies on a twofold rotation axis and is coordinated in a slightly distorted trigonal–prismatic environment. In...

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Detalles Bibliográficos
Autores principales: Chooset, Sirinart, Cunningham, Bryan, Kantacha, Anob, Zeller, Matthias, Wongnawa, Sumpun
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998447/
https://www.ncbi.nlm.nih.gov/pubmed/24764939
http://dx.doi.org/10.1107/S160053681400364X
Descripción
Sumario:The title complex, [Cd(C(9)H(7)O(2))(2)(H(2)O)(2)], was obtained as an unintended product of the reaction of cadmium nitrate with hexa­methyl­ene­tetra­mine and cinnamic acid. The Cd(II) ion lies on a twofold rotation axis and is coordinated in a slightly distorted trigonal–prismatic environment. In the crystal, the V-shaped mol­ecules are arranged in an inter­locking fashion along [010] and O—H⋯O hydrogen bonds link the mol­ecules, forming a two-dimensional network parallel to (001).

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