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Diaquabis(cinnamato-κ(2) O,O′)cadmium
The title complex, [Cd(C(9)H(7)O(2))(2)(H(2)O)(2)], was obtained as an unintended product of the reaction of cadmium nitrate with hexamethylenetetramine and cinnamic acid. The Cd(II) ion lies on a twofold rotation axis and is coordinated in a slightly distorted trigonal–prismatic environment. In...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998447/ https://www.ncbi.nlm.nih.gov/pubmed/24764939 http://dx.doi.org/10.1107/S160053681400364X |
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author | Chooset, Sirinart Cunningham, Bryan Kantacha, Anob Zeller, Matthias Wongnawa, Sumpun |
author_facet | Chooset, Sirinart Cunningham, Bryan Kantacha, Anob Zeller, Matthias Wongnawa, Sumpun |
author_sort | Chooset, Sirinart |
collection | PubMed |
description | The title complex, [Cd(C(9)H(7)O(2))(2)(H(2)O)(2)], was obtained as an unintended product of the reaction of cadmium nitrate with hexamethylenetetramine and cinnamic acid. The Cd(II) ion lies on a twofold rotation axis and is coordinated in a slightly distorted trigonal–prismatic environment. In the crystal, the V-shaped molecules are arranged in an interlocking fashion along [010] and O—H⋯O hydrogen bonds link the molecules, forming a two-dimensional network parallel to (001). |
format | Online Article Text |
id | pubmed-3998447 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984472014-04-24 Diaquabis(cinnamato-κ(2) O,O′)cadmium Chooset, Sirinart Cunningham, Bryan Kantacha, Anob Zeller, Matthias Wongnawa, Sumpun Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cd(C(9)H(7)O(2))(2)(H(2)O)(2)], was obtained as an unintended product of the reaction of cadmium nitrate with hexamethylenetetramine and cinnamic acid. The Cd(II) ion lies on a twofold rotation axis and is coordinated in a slightly distorted trigonal–prismatic environment. In the crystal, the V-shaped molecules are arranged in an interlocking fashion along [010] and O—H⋯O hydrogen bonds link the molecules, forming a two-dimensional network parallel to (001). International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998447/ /pubmed/24764939 http://dx.doi.org/10.1107/S160053681400364X Text en © Chooset et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Chooset, Sirinart Cunningham, Bryan Kantacha, Anob Zeller, Matthias Wongnawa, Sumpun Diaquabis(cinnamato-κ(2) O,O′)cadmium |
title | Diaquabis(cinnamato-κ(2)
O,O′)cadmium |
title_full | Diaquabis(cinnamato-κ(2)
O,O′)cadmium |
title_fullStr | Diaquabis(cinnamato-κ(2)
O,O′)cadmium |
title_full_unstemmed | Diaquabis(cinnamato-κ(2)
O,O′)cadmium |
title_short | Diaquabis(cinnamato-κ(2)
O,O′)cadmium |
title_sort | diaquabis(cinnamato-κ(2)
o,o′)cadmium |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998447/ https://www.ncbi.nlm.nih.gov/pubmed/24764939 http://dx.doi.org/10.1107/S160053681400364X |
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