Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)

In the title complex, [Mn(C(20)H(21)N(3))(2)](ClO(4))(2), two tridentate (2-methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine (L) ligands form the Mn(II) complex [MnL (2)](ClO(4))(2). The Mn(II) ion lies on a twofold axis and the complex cation is significantly distorted from regular octa­hedral geometr...

Descripción completa

Detalles Bibliográficos
Autores principales: Butcher, Ray J., Gultneh, Yilma, Yisgedu, T. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998448/
https://www.ncbi.nlm.nih.gov/pubmed/24764935
http://dx.doi.org/10.1107/S1600536814003055
Descripción
Sumario:In the title complex, [Mn(C(20)H(21)N(3))(2)](ClO(4))(2), two tridentate (2-methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine (L) ligands form the Mn(II) complex [MnL (2)](ClO(4))(2). The Mn(II) ion lies on a twofold axis and the complex cation is significantly distorted from regular octa­hedral geometry. The packing is stabilized by weak C—H⋯O inter­actions between the cations and anions, which link them into a zigzag ribbon along [101]. The perchlorate anion is disordered and was constrained to be tetra­hedral with two orientations having occupancies of 0.768 (4) and 0.232 (4). The 2-methylbenzyl moiety is also disordered over two sets of sites, with occupancies of 0.508 (15) and 0.492 (15).

Ejemplares similares