Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)

In the title complex, [Mn(C(20)H(21)N(3))(2)](ClO(4))(2), two tridentate (2-methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine (L) ligands form the Mn(II) complex [MnL (2)](ClO(4))(2). The Mn(II) ion lies on a twofold axis and the complex cation is significantly distorted from regular octa­hedral geometr...

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Autores principales: Butcher, Ray J., Gultneh, Yilma, Yisgedu, T. B.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998448/
https://www.ncbi.nlm.nih.gov/pubmed/24764935
http://dx.doi.org/10.1107/S1600536814003055
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author Butcher, Ray J.
Gultneh, Yilma
Yisgedu, T. B.
author_facet Butcher, Ray J.
Gultneh, Yilma
Yisgedu, T. B.
author_sort Butcher, Ray J.
collection PubMed
description In the title complex, [Mn(C(20)H(21)N(3))(2)](ClO(4))(2), two tridentate (2-methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine (L) ligands form the Mn(II) complex [MnL (2)](ClO(4))(2). The Mn(II) ion lies on a twofold axis and the complex cation is significantly distorted from regular octa­hedral geometry. The packing is stabilized by weak C—H⋯O inter­actions between the cations and anions, which link them into a zigzag ribbon along [101]. The perchlorate anion is disordered and was constrained to be tetra­hedral with two orientations having occupancies of 0.768 (4) and 0.232 (4). The 2-methylbenzyl moiety is also disordered over two sets of sites, with occupancies of 0.508 (15) and 0.492 (15).
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spelling pubmed-39984482014-04-24 Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate) Butcher, Ray J. Gultneh, Yilma Yisgedu, T. B. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title complex, [Mn(C(20)H(21)N(3))(2)](ClO(4))(2), two tridentate (2-methyl­benz­yl)bis­(pyridin-2-ylmeth­yl)amine (L) ligands form the Mn(II) complex [MnL (2)](ClO(4))(2). The Mn(II) ion lies on a twofold axis and the complex cation is significantly distorted from regular octa­hedral geometry. The packing is stabilized by weak C—H⋯O inter­actions between the cations and anions, which link them into a zigzag ribbon along [101]. The perchlorate anion is disordered and was constrained to be tetra­hedral with two orientations having occupancies of 0.768 (4) and 0.232 (4). The 2-methylbenzyl moiety is also disordered over two sets of sites, with occupancies of 0.508 (15) and 0.492 (15). International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998448/ /pubmed/24764935 http://dx.doi.org/10.1107/S1600536814003055 Text en © Butcher et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Butcher, Ray J.
Gultneh, Yilma
Yisgedu, T. B.
Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)
title Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)
title_full Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)
title_fullStr Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)
title_full_unstemmed Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)
title_short Bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κN)amine-κN]manganese(II) bis­(perchlorate)
title_sort bis[(2-methyl­benz­yl)bis­(pyridin-2-ylmethyl-κn)amine-κn]manganese(ii) bis­(perchlorate)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998448/
https://www.ncbi.nlm.nih.gov/pubmed/24764935
http://dx.doi.org/10.1107/S1600536814003055
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AT gultnehyilma bis2methylbenzylbispyridin2ylmethylknamineknmanganeseiibisperchlorate
AT yisgedutb bis2methylbenzylbispyridin2ylmethylknamineknmanganeseiibisperchlorate

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