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(Methoxymethylidene)dimethylazanium tetraphenylborate acetonitrile monosolvate
In the cation of the title salt, C(4)H(10)NO(+)·C(24)H(20)B(−)·C(2)H(3)N, the C—N bond lengths are 1.2864 (16), 1.4651 (17) and 1.4686 (16) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.2978 (15) Å shows double-bond character, pointing towards charge delocal...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998454/ https://www.ncbi.nlm.nih.gov/pubmed/24765028 http://dx.doi.org/10.1107/S1600536814003481 |
Sumario: | In the cation of the title salt, C(4)H(10)NO(+)·C(24)H(20)B(−)·C(2)H(3)N, the C—N bond lengths are 1.2864 (16), 1.4651 (17) and 1.4686 (16) Å, indicating double- and single-bond character, respectively. The C—O bond length of 1.2978 (15) Å shows double-bond character, pointing towards charge delocalization within the NCO plane of the iminium ion. C—H⋯π interactions are present between the methine H atom and two of the phenyl rings of the tetraphenylborate ion. The latter forms an aromatic pocket in which the cation is embedded. The iminium ion is further connected through a C—H⋯N hydrogen bond to the acetonitrile molecule. This leads to the formation of a two-dimensional supramolecular pattern along the bc plane. |
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