2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one

In the title compound, C(17)H(14)BrNO(3)S, the phenyl ring makes a dihedral angle of 89.78 (16)° with the plane of the indole ring system. The terminal Br atom and the methyl group are disordered over two sets of sites, with site occupancies of 0.860 (2) and 0.140 (2). In the crystal, mol­ecules are...

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Autores principales: Ramathilagam, C., Umarani, P. R., Saravanan, V., Mohanakrishnan, A. K., Gunasekaran, B., Manivannan, V.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998462/
https://www.ncbi.nlm.nih.gov/pubmed/24765002
http://dx.doi.org/10.1107/S1600536814002864
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author Ramathilagam, C.
Umarani, P. R.
Saravanan, V.
Mohanakrishnan, A. K.
Gunasekaran, B.
Manivannan, V.
author_facet Ramathilagam, C.
Umarani, P. R.
Saravanan, V.
Mohanakrishnan, A. K.
Gunasekaran, B.
Manivannan, V.
author_sort Ramathilagam, C.
collection PubMed
description In the title compound, C(17)H(14)BrNO(3)S, the phenyl ring makes a dihedral angle of 89.78 (16)° with the plane of the indole ring system. The terminal Br atom and the methyl group are disordered over two sets of sites, with site occupancies of 0.860 (2) and 0.140 (2). In the crystal, mol­ecules are linked into a chain along the b-axis direction by weak C—H⋯O hydrogen bonds. The chains are further linked by C—H⋯π inter­actions, forming layers parallel to the bc plane.
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spelling pubmed-39984622014-04-24 2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one Ramathilagam, C. Umarani, P. R. Saravanan, V. Mohanakrishnan, A. K. Gunasekaran, B. Manivannan, V. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(14)BrNO(3)S, the phenyl ring makes a dihedral angle of 89.78 (16)° with the plane of the indole ring system. The terminal Br atom and the methyl group are disordered over two sets of sites, with site occupancies of 0.860 (2) and 0.140 (2). In the crystal, mol­ecules are linked into a chain along the b-axis direction by weak C—H⋯O hydrogen bonds. The chains are further linked by C—H⋯π inter­actions, forming layers parallel to the bc plane. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998462/ /pubmed/24765002 http://dx.doi.org/10.1107/S1600536814002864 Text en © Ramathilagam et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ramathilagam, C.
Umarani, P. R.
Saravanan, V.
Mohanakrishnan, A. K.
Gunasekaran, B.
Manivannan, V.
2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one
title 2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one
title_full 2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one
title_fullStr 2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one
title_full_unstemmed 2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one
title_short 2-Bromo-1-(1-phenyl­sulfonyl-1H-indol-3-yl)propan-1-one
title_sort 2-bromo-1-(1-phenyl­sulfonyl-1h-indol-3-yl)propan-1-one
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998462/
https://www.ncbi.nlm.nih.gov/pubmed/24765002
http://dx.doi.org/10.1107/S1600536814002864
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