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[2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone)
In the title compound, C(34)H(25)NO(3), the five-membered heterocyclic ring adopts an envelope conformation with the N atom as the flap. The plane through the four basal atoms of this ring makes dihedral angles of 69.78 (13), 53.15 (12) and 86.42 (13)°, respectively, with the benzene rings of the be...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998464/ https://www.ncbi.nlm.nih.gov/pubmed/24765042 http://dx.doi.org/10.1107/S1600536814003250 |
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author | Sandhya, R. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_facet | Sandhya, R. Sithambaresan, M. Kurup, M. R. Prathapachandra |
author_sort | Sandhya, R. |
collection | PubMed |
description | In the title compound, C(34)H(25)NO(3), the five-membered heterocyclic ring adopts an envelope conformation with the N atom as the flap. The plane through the four basal atoms of this ring makes dihedral angles of 69.78 (13), 53.15 (12) and 86.42 (13)°, respectively, with the benzene rings of the benzyl group and the two phenylmethanone groups at the 4 and 5 positions, and of 78.60 (11)° with the naphthalenyl system. In the crystal, the molecules are linked through C—H⋯O and C—H⋯π contacts into layers parallel to (101). |
format | Online Article Text |
id | pubmed-3998464 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984642014-04-24 [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) Sandhya, R. Sithambaresan, M. Kurup, M. R. Prathapachandra Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(34)H(25)NO(3), the five-membered heterocyclic ring adopts an envelope conformation with the N atom as the flap. The plane through the four basal atoms of this ring makes dihedral angles of 69.78 (13), 53.15 (12) and 86.42 (13)°, respectively, with the benzene rings of the benzyl group and the two phenylmethanone groups at the 4 and 5 positions, and of 78.60 (11)° with the naphthalenyl system. In the crystal, the molecules are linked through C—H⋯O and C—H⋯π contacts into layers parallel to (101). International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998464/ /pubmed/24765042 http://dx.doi.org/10.1107/S1600536814003250 Text en © Sandhya et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Sandhya, R. Sithambaresan, M. Kurup, M. R. Prathapachandra [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
title | [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
title_full | [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
title_fullStr | [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
title_full_unstemmed | [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
title_short | [2-Benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
title_sort | [2-benzyl-3-(naphthalen-1-yl)-2,3-dihydro-1,2-oxazole-4,5-diyl]bis(phenylmethanone) |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998464/ https://www.ncbi.nlm.nih.gov/pubmed/24765042 http://dx.doi.org/10.1107/S1600536814003250 |
work_keys_str_mv | AT sandhyar 2benzyl3naphthalen1yl23dihydro12oxazole45diylbisphenylmethanone AT sithambaresanm 2benzyl3naphthalen1yl23dihydro12oxazole45diylbisphenylmethanone AT kurupmrprathapachandra 2benzyl3naphthalen1yl23dihydro12oxazole45diylbisphenylmethanone |