2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate

In the title compound, C(16)H(8)N(6)O(2)S(2)·2C(2)H(6)OS, the phenanthroline mol­ecule resides on a twofold axis, and the asymmetric unit also contains a slightly disordered [occupancy ratio for S atom of 0.95 (3):0.047 (3)] mol­ecule of dimethyl sulfoxide. The O atoms of the solvent mol­ecule accep...

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Autores principales: Rahman, Md. A, Karim, Mohammad, Arifuzzaman, Md., Siddiquee, Tasneem, Daniels, Lee M.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998466/
https://www.ncbi.nlm.nih.gov/pubmed/24765020
http://dx.doi.org/10.1107/S1600536814003304
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author Rahman, Md. A
Karim, Mohammad
Arifuzzaman, Md.
Siddiquee, Tasneem
Daniels, Lee M.
author_facet Rahman, Md. A
Karim, Mohammad
Arifuzzaman, Md.
Siddiquee, Tasneem
Daniels, Lee M.
author_sort Rahman, Md. A
collection PubMed
description In the title compound, C(16)H(8)N(6)O(2)S(2)·2C(2)H(6)OS, the phenanthroline mol­ecule resides on a twofold axis, and the asymmetric unit also contains a slightly disordered [occupancy ratio for S atom of 0.95 (3):0.047 (3)] mol­ecule of dimethyl sulfoxide. The O atoms of the solvent mol­ecule accept hydrogen bonds from the N—H groups of the five-membered 2,3-di­hydro-1,3,4-oxa­diazole-2-thione ring. This ring is nearly coplanar with the phenanthroline ring, with a dihedral angle between their least-squares planes of 8.86 (6)°. In the crystal, the mol­ecules are linked by C—H⋯O inter­actions.
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spelling pubmed-39984662014-04-24 2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate Rahman, Md. A Karim, Mohammad Arifuzzaman, Md. Siddiquee, Tasneem Daniels, Lee M. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(16)H(8)N(6)O(2)S(2)·2C(2)H(6)OS, the phenanthroline mol­ecule resides on a twofold axis, and the asymmetric unit also contains a slightly disordered [occupancy ratio for S atom of 0.95 (3):0.047 (3)] mol­ecule of dimethyl sulfoxide. The O atoms of the solvent mol­ecule accept hydrogen bonds from the N—H groups of the five-membered 2,3-di­hydro-1,3,4-oxa­diazole-2-thione ring. This ring is nearly coplanar with the phenanthroline ring, with a dihedral angle between their least-squares planes of 8.86 (6)°. In the crystal, the mol­ecules are linked by C—H⋯O inter­actions. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998466/ /pubmed/24765020 http://dx.doi.org/10.1107/S1600536814003304 Text en © Rahman et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Rahman, Md. A
Karim, Mohammad
Arifuzzaman, Md.
Siddiquee, Tasneem
Daniels, Lee M.
2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
title 2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
title_full 2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
title_fullStr 2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
title_full_unstemmed 2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
title_short 2,9-Bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
title_sort 2,9-bis(5-sulfanylidene-4,5-di­hydro-1,3,4-oxa­diazol-2-yl)-1,10-phenanthroline dimethyl sulfoxide disolvate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998466/
https://www.ncbi.nlm.nih.gov/pubmed/24765020
http://dx.doi.org/10.1107/S1600536814003304
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