4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine

In the title compound, C(20)H(14)F(3)NS(2), the seven-membered thia­zepine ring adopts a slightly distorted twist–boat conformation. The mean plane of the five-membered thio­phene ring fused to the thia­zepine ring is twisted by 32.3 (3) and 55.6 (4)° from the benzene and phenyl rings, respectively....

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Detalles Bibliográficos
Autores principales: Manjunath, B. C., Manjula, M., Raghavendra, K. R., Ajay Kumar, K., Lokanath, N. K.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998467/
https://www.ncbi.nlm.nih.gov/pubmed/24764977
http://dx.doi.org/10.1107/S1600536814002529
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author Manjunath, B. C.
Manjula, M.
Raghavendra, K. R.
Ajay Kumar, K.
Lokanath, N. K.
author_facet Manjunath, B. C.
Manjula, M.
Raghavendra, K. R.
Ajay Kumar, K.
Lokanath, N. K.
author_sort Manjunath, B. C.
collection PubMed
description In the title compound, C(20)H(14)F(3)NS(2), the seven-membered thia­zepine ring adopts a slightly distorted twist–boat conformation. The mean plane of the five-membered thio­phene ring fused to the thia­zepine ring is twisted by 32.3 (3) and 55.6 (4)° from the benzene and phenyl rings, respectively. In the crystal, inversion dimers linked by pairs of weak C—H⋯N inter­actions are observed.
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spelling pubmed-39984672014-04-24 4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine Manjunath, B. C. Manjula, M. Raghavendra, K. R. Ajay Kumar, K. Lokanath, N. K. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(20)H(14)F(3)NS(2), the seven-membered thia­zepine ring adopts a slightly distorted twist–boat conformation. The mean plane of the five-membered thio­phene ring fused to the thia­zepine ring is twisted by 32.3 (3) and 55.6 (4)° from the benzene and phenyl rings, respectively. In the crystal, inversion dimers linked by pairs of weak C—H⋯N inter­actions are observed. International Union of Crystallography 2014-02-08 /pmc/articles/PMC3998467/ /pubmed/24764977 http://dx.doi.org/10.1107/S1600536814002529 Text en © Manjunath et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Manjunath, B. C.
Manjula, M.
Raghavendra, K. R.
Ajay Kumar, K.
Lokanath, N. K.
4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
title 4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
title_full 4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
title_fullStr 4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
title_full_unstemmed 4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
title_short 4-(Thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
title_sort 4-(thio­phen-2-yl)-2-[4-(tri­fluoro­meth­yl)phen­yl]-2,3-di­hydro-1,5-benzo­thia­zepine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998467/
https://www.ncbi.nlm.nih.gov/pubmed/24764977
http://dx.doi.org/10.1107/S1600536814002529
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