3-Anilino-5,5-di­methyl­cyclo­hex-2-enone

In the title mol­ecule, C(14)H(17)NO, the 5,5-di­methyl­cyclo­hex-2-enone moiety is attached to an aniline group, the dihedral angle subtended [54.43 (3)°] indicating a significant twist. The hexaneone ring has a half-chair conformation with the C atom bearing two methyl groups lying 0.6384 (8) Å ab...

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Autores principales: Boulebd, Houssem, Bouraiou, Abdelmalek, Bouacida, Sofiane, Merazig, Hocine, Belfaitah, Ali
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998468/
https://www.ncbi.nlm.nih.gov/pubmed/24764957
http://dx.doi.org/10.1107/S160053681400186X
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author Boulebd, Houssem
Bouraiou, Abdelmalek
Bouacida, Sofiane
Merazig, Hocine
Belfaitah, Ali
author_facet Boulebd, Houssem
Bouraiou, Abdelmalek
Bouacida, Sofiane
Merazig, Hocine
Belfaitah, Ali
author_sort Boulebd, Houssem
collection PubMed
description In the title mol­ecule, C(14)H(17)NO, the 5,5-di­methyl­cyclo­hex-2-enone moiety is attached to an aniline group, the dihedral angle subtended [54.43 (3)°] indicating a significant twist. The hexaneone ring has a half-chair conformation with the C atom bearing two methyl groups lying 0.6384 (8) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0107 Å). The crystal packing can be described as alternating layers parallel to (-101), which are consolidated by N—H⋯O hydrogen bonds and C—H⋯π inter­actions.
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spelling pubmed-39984682014-04-24 3-Anilino-5,5-di­methyl­cyclo­hex-2-enone Boulebd, Houssem Bouraiou, Abdelmalek Bouacida, Sofiane Merazig, Hocine Belfaitah, Ali Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title mol­ecule, C(14)H(17)NO, the 5,5-di­methyl­cyclo­hex-2-enone moiety is attached to an aniline group, the dihedral angle subtended [54.43 (3)°] indicating a significant twist. The hexaneone ring has a half-chair conformation with the C atom bearing two methyl groups lying 0.6384 (8) Å above the plane of the five remaining atoms (r.m.s. deviation = 0.0107 Å). The crystal packing can be described as alternating layers parallel to (-101), which are consolidated by N—H⋯O hydrogen bonds and C—H⋯π inter­actions. International Union of Crystallography 2014-02-05 /pmc/articles/PMC3998468/ /pubmed/24764957 http://dx.doi.org/10.1107/S160053681400186X Text en © Boulebd et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Boulebd, Houssem
Bouraiou, Abdelmalek
Bouacida, Sofiane
Merazig, Hocine
Belfaitah, Ali
3-Anilino-5,5-di­methyl­cyclo­hex-2-enone
title 3-Anilino-5,5-di­methyl­cyclo­hex-2-enone
title_full 3-Anilino-5,5-di­methyl­cyclo­hex-2-enone
title_fullStr 3-Anilino-5,5-di­methyl­cyclo­hex-2-enone
title_full_unstemmed 3-Anilino-5,5-di­methyl­cyclo­hex-2-enone
title_short 3-Anilino-5,5-di­methyl­cyclo­hex-2-enone
title_sort 3-anilino-5,5-di­methyl­cyclo­hex-2-enone
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998468/
https://www.ncbi.nlm.nih.gov/pubmed/24764957
http://dx.doi.org/10.1107/S160053681400186X
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