[N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)

The complex molecule in the title compound, [NiBr(2)(C(36)H(40)N(2))], has mirror symmetry. The Ni(II) atom and two Br atoms are located on the mirror plane. The Ni(II) atom is four-coordinated by the two Br atoms and two N atoms from an N,N′-bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine liga...

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Detalles Bibliográficos
Autores principales: Yuan, Jianchao, Xia, Jingjing, Xu, Weibing, Mu, Yanqiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998469/
https://www.ncbi.nlm.nih.gov/pubmed/24764936
http://dx.doi.org/10.1107/S160053681400292X
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author Yuan, Jianchao
Xia, Jingjing
Xu, Weibing
Mu, Yanqiong
author_facet Yuan, Jianchao
Xia, Jingjing
Xu, Weibing
Mu, Yanqiong
author_sort Yuan, Jianchao
collection PubMed
description The complex molecule in the title compound, [NiBr(2)(C(36)H(40)N(2))], has mirror symmetry. The Ni(II) atom and two Br atoms are located on the mirror plane. The Ni(II) atom is four-coordinated by the two Br atoms and two N atoms from an N,N′-bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine ligand in a distorted tetra­hedral geometry. The dihedral angle formed between the two adjacent benzene rings is 47.1 (1)°.
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spelling pubmed-39984692014-04-24 [N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II) Yuan, Jianchao Xia, Jingjing Xu, Weibing Mu, Yanqiong Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The complex molecule in the title compound, [NiBr(2)(C(36)H(40)N(2))], has mirror symmetry. The Ni(II) atom and two Br atoms are located on the mirror plane. The Ni(II) atom is four-coordinated by the two Br atoms and two N atoms from an N,N′-bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine ligand in a distorted tetra­hedral geometry. The dihedral angle formed between the two adjacent benzene rings is 47.1 (1)°. International Union of Crystallography 2014-02-15 /pmc/articles/PMC3998469/ /pubmed/24764936 http://dx.doi.org/10.1107/S160053681400292X Text en © Yuan et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Yuan, Jianchao
Xia, Jingjing
Xu, Weibing
Mu, Yanqiong
[N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)
title [N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)
title_full [N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)
title_fullStr [N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)
title_full_unstemmed [N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)
title_short [N,N′-Bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) N,N′]di­bromido­nickel(II)
title_sort [n,n′-bis(2,6-diethyl-4-phenyl­phen­yl)butane-2,3-di­imine-κ(2) n,n′]di­bromido­nickel(ii)
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998469/
https://www.ncbi.nlm.nih.gov/pubmed/24764936
http://dx.doi.org/10.1107/S160053681400292X
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