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1-Methylpiperazine-1,4-dium bis(hydrogen oxalate)
In the crystal structure of the title compound, C(5)H(14)N(2) (2+)·2HC(2)O(4) (−), the two crystallographically independent hydrogen oxalate anions are linked by strong intermolecular O—H⋯O hydrogen bonds, forming two independent corrugated chains parallel to the b axis. These chains are further co...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998474/ https://www.ncbi.nlm.nih.gov/pubmed/24765024 http://dx.doi.org/10.1107/S1600536814003559 |
Sumario: | In the crystal structure of the title compound, C(5)H(14)N(2) (2+)·2HC(2)O(4) (−), the two crystallographically independent hydrogen oxalate anions are linked by strong intermolecular O—H⋯O hydrogen bonds, forming two independent corrugated chains parallel to the b axis. These chains are further connected by N—H⋯O and C—H⋯O hydrogen bonds originating from the organic cations, forming a three-dimensional network. The diprotonated piperazine ring adopts a chair conformation, with the methyl group occupying an equatorial position. |
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