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(E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one

The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-meth­oxy­phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo­penta­dienyl (Cps) ring and the unsubstituted cyclo­penta­dien...

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Detalles Bibliográficos
Autores principales: Otaño Vega, Myrna R., Rivero, Kennett I., Montes González, Ingrid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998481/
https://www.ncbi.nlm.nih.gov/pubmed/24764940
http://dx.doi.org/10.1107/S1600536814003912
Descripción
Sumario:The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-meth­oxy­phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo­penta­dienyl (Cps) ring and the unsubstituted cyclo­penta­dienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds into supra­molecular chains running along the b-axis direction.