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(E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one
The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-methoxyphenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclopentadienyl (Cps) ring and the unsubstituted cyclopentadien...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998481/ https://www.ncbi.nlm.nih.gov/pubmed/24764940 http://dx.doi.org/10.1107/S1600536814003912 |
Sumario: | The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-methoxyphenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclopentadienyl (Cps) ring and the unsubstituted cyclopentadienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds into supramolecular chains running along the b-axis direction. |
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