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(E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one
The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-methoxyphenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclopentadienyl (Cps) ring and the unsubstituted cyclopentadien...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998481/ https://www.ncbi.nlm.nih.gov/pubmed/24764940 http://dx.doi.org/10.1107/S1600536814003912 |
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author | Otaño Vega, Myrna R. Rivero, Kennett I. Montes González, Ingrid |
author_facet | Otaño Vega, Myrna R. Rivero, Kennett I. Montes González, Ingrid |
author_sort | Otaño Vega, Myrna R. |
collection | PubMed |
description | The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-methoxyphenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclopentadienyl (Cps) ring and the unsubstituted cyclopentadienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds into supramolecular chains running along the b-axis direction. |
format | Online Article Text |
id | pubmed-3998481 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984812014-04-24 (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one Otaño Vega, Myrna R. Rivero, Kennett I. Montes González, Ingrid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-methoxyphenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclopentadienyl (Cps) ring and the unsubstituted cyclopentadienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, molecules are linked by weak C—H⋯O hydrogen bonds into supramolecular chains running along the b-axis direction. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998481/ /pubmed/24764940 http://dx.doi.org/10.1107/S1600536814003912 Text en © Otaño Vega et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Metal-Organic Papers Otaño Vega, Myrna R. Rivero, Kennett I. Montes González, Ingrid (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
title | (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
title_full | (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
title_fullStr | (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
title_full_unstemmed | (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
title_short | (E)-1-Ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
title_sort | (e)-1-ferrocenyl-3-(2-methoxyphenyl)prop-2-en-1-one |
topic | Metal-Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998481/ https://www.ncbi.nlm.nih.gov/pubmed/24764940 http://dx.doi.org/10.1107/S1600536814003912 |
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