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(E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one

The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-meth­oxy­phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo­penta­dienyl (Cps) ring and the unsubstituted cyclo­penta­dien...

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Autores principales: Otaño Vega, Myrna R., Rivero, Kennett I., Montes González, Ingrid
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998481/
https://www.ncbi.nlm.nih.gov/pubmed/24764940
http://dx.doi.org/10.1107/S1600536814003912
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author Otaño Vega, Myrna R.
Rivero, Kennett I.
Montes González, Ingrid
author_facet Otaño Vega, Myrna R.
Rivero, Kennett I.
Montes González, Ingrid
author_sort Otaño Vega, Myrna R.
collection PubMed
description The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-meth­oxy­phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo­penta­dienyl (Cps) ring and the unsubstituted cyclo­penta­dienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds into supra­molecular chains running along the b-axis direction.
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spelling pubmed-39984812014-04-24 (E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one Otaño Vega, Myrna R. Rivero, Kennett I. Montes González, Ingrid Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The structure of the title compound, [Fe(C(5)H(5))(C(15)H(13)O(2))], consists of a ferrocenyl moiety and a 2-meth­oxy­phenyl group linked through a prop-2-en-1-one spacer in an E conformation. In the ferrocene unit, the substituted cyclo­penta­dienyl (Cps) ring and the unsubstituted cyclo­penta­dienyl ring (Cp) are almost parallel to one another [dihedral angle = 1.78 (14)°], and the Cp and Cps rings are in a gauche conformation. The benzene ring is twisted by 10.02 (14) and 11.38 (11)° with respect to the Cp and Cps rings, respectively. In the crystal, mol­ecules are linked by weak C—H⋯O hydrogen bonds into supra­molecular chains running along the b-axis direction. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998481/ /pubmed/24764940 http://dx.doi.org/10.1107/S1600536814003912 Text en © Otaño Vega et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Otaño Vega, Myrna R.
Rivero, Kennett I.
Montes González, Ingrid
(E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
title (E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
title_full (E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
title_fullStr (E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
title_full_unstemmed (E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
title_short (E)-1-Ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
title_sort (e)-1-ferrocenyl-3-(2-meth­oxy­phen­yl)prop-2-en-1-one
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998481/
https://www.ncbi.nlm.nih.gov/pubmed/24764940
http://dx.doi.org/10.1107/S1600536814003912
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