Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate

The title compound, C(16)H(13)NO(6), exhibits a biphenyl unit with a dihedral angle between the two aryl rings of 56.01 (5)°. The two ester groups vary slightly from planarity, with ar­yl–ester dihedral angles of 4.57 (5) and 16.73 (5)°. The nitro group is turned from the aromatic unit with an ar­yl...

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Autores principales: Vieira, Vanessa C. M., Golen, James A., Rheingold, Arnold L., Manke, David R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998483/
https://www.ncbi.nlm.nih.gov/pubmed/24765053
http://dx.doi.org/10.1107/S1600536814004218
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author Vieira, Vanessa C. M.
Golen, James A.
Rheingold, Arnold L.
Manke, David R.
author_facet Vieira, Vanessa C. M.
Golen, James A.
Rheingold, Arnold L.
Manke, David R.
author_sort Vieira, Vanessa C. M.
collection PubMed
description The title compound, C(16)H(13)NO(6), exhibits a biphenyl unit with a dihedral angle between the two aryl rings of 56.01 (5)°. The two ester groups vary slightly from planarity, with ar­yl–ester dihedral angles of 4.57 (5) and 16.73 (5)°. The nitro group is turned from the aromatic unit with an ar­yl–nitro dihedral angle of 48.66 (4)°. In the crystal, mol­ecules are connected by weak C—H⋯O inter­actions, forming a three-dimensional network.
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spelling pubmed-39984832014-04-24 Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate Vieira, Vanessa C. M. Golen, James A. Rheingold, Arnold L. Manke, David R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(16)H(13)NO(6), exhibits a biphenyl unit with a dihedral angle between the two aryl rings of 56.01 (5)°. The two ester groups vary slightly from planarity, with ar­yl–ester dihedral angles of 4.57 (5) and 16.73 (5)°. The nitro group is turned from the aromatic unit with an ar­yl–nitro dihedral angle of 48.66 (4)°. In the crystal, mol­ecules are connected by weak C—H⋯O inter­actions, forming a three-dimensional network. International Union of Crystallography 2014-02-28 /pmc/articles/PMC3998483/ /pubmed/24765053 http://dx.doi.org/10.1107/S1600536814004218 Text en © Vieira et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Vieira, Vanessa C. M.
Golen, James A.
Rheingold, Arnold L.
Manke, David R.
Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
title Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
title_full Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
title_fullStr Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
title_full_unstemmed Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
title_short Dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
title_sort dimethyl 2-nitro­biphenyl-4,4′-di­carboxyl­ate
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998483/
https://www.ncbi.nlm.nih.gov/pubmed/24765053
http://dx.doi.org/10.1107/S1600536814004218
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AT mankedavidr dimethyl2nitrobiphenyl44dicarboxylate

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