Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc

In the title compound, [ZnCl(2)(C(14)H(12)N(2))(2)], the Zn(II) atom exhibits a distorted tetra­hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihed...

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Detalles Bibliográficos
Autores principales: Bouhfid, Rachid, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998485/
https://www.ncbi.nlm.nih.gov/pubmed/24764954
http://dx.doi.org/10.1107/S1600536814002840
Descripción
Sumario:In the title compound, [ZnCl(2)(C(14)H(12)N(2))(2)], the Zn(II) atom exhibits a distorted tetra­hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7 (2) and 81.5 (2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015 (3) and 0.020 (2) Å] and form a dihedral angle of 78.09 (8)°. In the crystal, centrosymmetrically related mol­ecules are linked by pairs of C—H⋯Cl hydrogen bonds into chains parallel to the a axis.

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