Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc

In the title compound, [ZnCl(2)(C(14)H(12)N(2))(2)], the Zn(II) atom exhibits a distorted tetra­hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihed...

Descripción completa

Detalles Bibliográficos
Autores principales: Bouhfid, Rachid, Essassi, El Mokhtar, Saadi, Mohamed, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998485/
https://www.ncbi.nlm.nih.gov/pubmed/24764954
http://dx.doi.org/10.1107/S1600536814002840
_version_ 1782313372306374656
author Bouhfid, Rachid
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_facet Bouhfid, Rachid
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
author_sort Bouhfid, Rachid
collection PubMed
description In the title compound, [ZnCl(2)(C(14)H(12)N(2))(2)], the Zn(II) atom exhibits a distorted tetra­hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7 (2) and 81.5 (2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015 (3) and 0.020 (2) Å] and form a dihedral angle of 78.09 (8)°. In the crystal, centrosymmetrically related mol­ecules are linked by pairs of C—H⋯Cl hydrogen bonds into chains parallel to the a axis.
format Online
Article
Text
id pubmed-3998485
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39984852014-04-24 Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc Bouhfid, Rachid Essassi, El Mokhtar Saadi, Mohamed El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers In the title compound, [ZnCl(2)(C(14)H(12)N(2))(2)], the Zn(II) atom exhibits a distorted tetra­hedral coordination geometry involving two chloride anions and two N-atom donors from 1-benzyl-1H-benzimidazole ligands. In both ligands, the benzyl and benzimidazole rings are nearly perpendicular [dihedral angles = 81.7 (2) and 81.5 (2)°]. The two benzimidazole systems are essentially planar [maximum deviations = 0.015 (3) and 0.020 (2) Å] and form a dihedral angle of 78.09 (8)°. In the crystal, centrosymmetrically related mol­ecules are linked by pairs of C—H⋯Cl hydrogen bonds into chains parallel to the a axis. International Union of Crystallography 2014-02-12 /pmc/articles/PMC3998485/ /pubmed/24764954 http://dx.doi.org/10.1107/S1600536814002840 Text en © Bouhfid et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Bouhfid, Rachid
Essassi, El Mokhtar
Saadi, Mohamed
El Ammari, Lahcen
Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc
title Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc
title_full Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc
title_fullStr Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc
title_full_unstemmed Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc
title_short Bis(1-benzyl-1H-benzimidazole-κN (3))di­chlorido­zinc
title_sort bis(1-benzyl-1h-benzimidazole-κn (3))di­chlorido­zinc
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998485/
https://www.ncbi.nlm.nih.gov/pubmed/24764954
http://dx.doi.org/10.1107/S1600536814002840
work_keys_str_mv AT bouhfidrachid bis1benzyl1hbenzimidazolekn3dichloridozinc
AT essassielmokhtar bis1benzyl1hbenzimidazolekn3dichloridozinc
AT saadimohamed bis1benzyl1hbenzimidazolekn3dichloridozinc
AT elammarilahcen bis1benzyl1hbenzimidazolekn3dichloridozinc

Ejemplares similares