Cargando…

Methyl 3′-benzyl-4′-(2,4-di­chloro­phen­yl)-1′-methyl-2-oxo-1-propyl­spiro­[indoline-3,2′-pyrrolidine]-3′-carboxy­l­ate

In the title compound, C(30)H(30)Cl(2)N(2)O(3), the indole ring system is roughly planar, with a maximum deviation of 0.1039 (18) Å for the carbonyl C atom, and makes a dihedral angle of 86.61 (9)° with the mean plane of the pyrrolidine ring. This spiro pyrrolidine ring adopts an envelope conformati...

Descripción completa

Detalles Bibliográficos
Autores principales: Karthikeyan, S., Sethusankar, K., Devaraj, Anthonisamy, Bakthadoss, Manickam
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998486/
https://www.ncbi.nlm.nih.gov/pubmed/24764986
http://dx.doi.org/10.1107/S1600536814002621
Descripción
Sumario:In the title compound, C(30)H(30)Cl(2)N(2)O(3), the indole ring system is roughly planar, with a maximum deviation of 0.1039 (18) Å for the carbonyl C atom, and makes a dihedral angle of 86.61 (9)° with the mean plane of the pyrrolidine ring. This spiro pyrrolidine ring adopts an envelope conformation with the N atom at the flap position. The pyrrole ring of the indole ring system adopts a twisted conformation on the C—C(=O) bond. The mol­ecular structure is stabilized by an intra­molecular C—H⋯O hydrogen bond, which generates an S(6) ring motif, and a π–π inter­action [centroid–centroid distance = 3.6577 (12) Å] involving the 2,4-di­chloro­phenyl ring and the benzyl ring. In the crystal, mol­ecules are linked via C—H⋯O hydrogen bonds, forming C(9) chains running parallel to [10-1].