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5-Bromo-3-cyclohexylsulfinyl-2,4,6-trimethyl-1-benzofuran
In the title compound, C(17)H(21)BrO(2)S, the cyclohexyl ring adopts a chair conformation and the arylsulfinyl unit is positioned equatorially relative to the cyclohexyl group. The benzofuran unit is essentially planar, with an r.m.s. deviation of 0.016 (2) Å. In the crystal, molecules are link...
Autores principales: | , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998487/ https://www.ncbi.nlm.nih.gov/pubmed/24765011 http://dx.doi.org/10.1107/S1600536814003171 |
Sumario: | In the title compound, C(17)H(21)BrO(2)S, the cyclohexyl ring adopts a chair conformation and the arylsulfinyl unit is positioned equatorially relative to the cyclohexyl group. The benzofuran unit is essentially planar, with an r.m.s. deviation of 0.016 (2) Å. In the crystal, molecules are linked by weak C—H⋯O, C—H⋯π and Br⋯π [3.663 (2) Å] interactions, resulting in a three-dimensional network. A Br⋯Br [3.6838 (6) Å] contact is observed. The O atom of the sulfinyl group is disordered over two orientations with an occupancy ratio of 0.863 (5):0.137 (5). |
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