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2-Cycloheptylidene-N-phenylhydrazinecarbothioamide
In the title compound, C(14)H(19)N(3)S, the seven-membered cycloheptane ring adopts a chair conformation. An intramolecular N—H⋯N hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. An intramolecular C—H⋯S contact also occurs. In the crystal, pairs of mo...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998488/ https://www.ncbi.nlm.nih.gov/pubmed/24765045 http://dx.doi.org/10.1107/S1600536814003948 |
Sumario: | In the title compound, C(14)H(19)N(3)S, the seven-membered cycloheptane ring adopts a chair conformation. An intramolecular N—H⋯N hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. An intramolecular C—H⋯S contact also occurs. In the crystal, pairs of molecules form centrosymmetric dimers through N—H⋯S hydrogen bonds [graph-set R (2) (2)(8)]. These dimers are connected by C—H⋯S interactions with an R (2) (2)(14) motif. |
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