2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide

In the title compound, C(14)H(19)N(3)S, the seven-membered cyclo­heptane ring adopts a chair conformation. An intra­molecular N—H⋯N hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. An intra­molecular C—H⋯S contact also occurs. In the crystal, pairs of mo...

Descripción completa

Detalles Bibliográficos
Autores principales: Akkurt, Mehmet, Mohamed, Shaaban K., Mague, Joel T., Hassan, Alaa A., Albayati, Mustafa R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998488/
https://www.ncbi.nlm.nih.gov/pubmed/24765045
http://dx.doi.org/10.1107/S1600536814003948
_version_ 1782313372981657600
author Akkurt, Mehmet
Mohamed, Shaaban K.
Mague, Joel T.
Hassan, Alaa A.
Albayati, Mustafa R.
author_facet Akkurt, Mehmet
Mohamed, Shaaban K.
Mague, Joel T.
Hassan, Alaa A.
Albayati, Mustafa R.
author_sort Akkurt, Mehmet
collection PubMed
description In the title compound, C(14)H(19)N(3)S, the seven-membered cyclo­heptane ring adopts a chair conformation. An intra­molecular N—H⋯N hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. An intra­molecular C—H⋯S contact also occurs. In the crystal, pairs of mol­ecules form centrosymmetric dimers through N—H⋯S hydrogen bonds [graph-set R (2) (2)(8)]. These dimers are connected by C—H⋯S inter­actions with an R (2) (2)(14) motif.
format Online
Article
Text
id pubmed-3998488
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39984882014-04-24 2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide Akkurt, Mehmet Mohamed, Shaaban K. Mague, Joel T. Hassan, Alaa A. Albayati, Mustafa R. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(14)H(19)N(3)S, the seven-membered cyclo­heptane ring adopts a chair conformation. An intra­molecular N—H⋯N hydrogen bond [graph-set motif S(5)] is present in the N—N—C—N chain between the ring systems. An intra­molecular C—H⋯S contact also occurs. In the crystal, pairs of mol­ecules form centrosymmetric dimers through N—H⋯S hydrogen bonds [graph-set R (2) (2)(8)]. These dimers are connected by C—H⋯S inter­actions with an R (2) (2)(14) motif. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998488/ /pubmed/24765045 http://dx.doi.org/10.1107/S1600536814003948 Text en © Akkurt et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Akkurt, Mehmet
Mohamed, Shaaban K.
Mague, Joel T.
Hassan, Alaa A.
Albayati, Mustafa R.
2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide
title 2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide
title_full 2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide
title_fullStr 2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide
title_full_unstemmed 2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide
title_short 2-Cyclo­heptyl­idene-N-phenyl­hydrazine­carbo­thio­amide
title_sort 2-cyclo­heptyl­idene-n-phenyl­hydrazine­carbo­thio­amide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998488/
https://www.ncbi.nlm.nih.gov/pubmed/24765045
http://dx.doi.org/10.1107/S1600536814003948
work_keys_str_mv AT akkurtmehmet 2cycloheptylidenenphenylhydrazinecarbothioamide
AT mohamedshaabank 2cycloheptylidenenphenylhydrazinecarbothioamide
AT maguejoelt 2cycloheptylidenenphenylhydrazinecarbothioamide
AT hassanalaaa 2cycloheptylidenenphenylhydrazinecarbothioamide
AT albayatimustafar 2cycloheptylidenenphenylhydrazinecarbothioamide

Ejemplares similares