Twinned caesium cerium(IV) penta­fluoride

Single-crystals of CsCeF(5) were synthesized hydro­thermally. The crystal under investigation was twinned by pseudo-merohedry with a twofold rotation around the c axis as an additional twinning operation. The crystal structure is built of layers of distorted edge- and corner-sharing CeF(8) square-an...

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Detalles Bibliográficos
Autores principales: Grzechnik, Andrzej, Underwood, Christopher C., Kolis, Joseph W.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Inorganic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998492/
https://www.ncbi.nlm.nih.gov/pubmed/24764931
http://dx.doi.org/10.1107/S1600536814003286
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author Grzechnik, Andrzej
Underwood, Christopher C.
Kolis, Joseph W.
author_facet Grzechnik, Andrzej
Underwood, Christopher C.
Kolis, Joseph W.
author_sort Grzechnik, Andrzej
collection PubMed
description Single-crystals of CsCeF(5) were synthesized hydro­thermally. The crystal under investigation was twinned by pseudo-merohedry with a twofold rotation around the c axis as an additional twinning operation. The crystal structure is built of layers of distorted edge- and corner-sharing CeF(8) square-anti­prisms. The Cs(+) cations are located between the layers and exhibit coordination numbers of nine. Upon compression, CsCeF(5) undergoes an irreversible phase transition at about 1 GPa.
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spelling pubmed-39984922014-04-24 Twinned caesium cerium(IV) penta­fluoride Grzechnik, Andrzej Underwood, Christopher C. Kolis, Joseph W. Acta Crystallogr Sect E Struct Rep Online Inorganic Papers Single-crystals of CsCeF(5) were synthesized hydro­thermally. The crystal under investigation was twinned by pseudo-merohedry with a twofold rotation around the c axis as an additional twinning operation. The crystal structure is built of layers of distorted edge- and corner-sharing CeF(8) square-anti­prisms. The Cs(+) cations are located between the layers and exhibit coordination numbers of nine. Upon compression, CsCeF(5) undergoes an irreversible phase transition at about 1 GPa. International Union of Crystallography 2014-02-19 /pmc/articles/PMC3998492/ /pubmed/24764931 http://dx.doi.org/10.1107/S1600536814003286 Text en © Grzechnik et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Inorganic Papers
Grzechnik, Andrzej
Underwood, Christopher C.
Kolis, Joseph W.
Twinned caesium cerium(IV) penta­fluoride
title Twinned caesium cerium(IV) penta­fluoride
title_full Twinned caesium cerium(IV) penta­fluoride
title_fullStr Twinned caesium cerium(IV) penta­fluoride
title_full_unstemmed Twinned caesium cerium(IV) penta­fluoride
title_short Twinned caesium cerium(IV) penta­fluoride
title_sort twinned caesium cerium(iv) penta­fluoride
topic Inorganic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998492/
https://www.ncbi.nlm.nih.gov/pubmed/24764931
http://dx.doi.org/10.1107/S1600536814003286
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AT kolisjosephw twinnedcaesiumceriumivpentafluoride

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