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3-(2,3-Dioxoindolin-1-yl)propane­nitrile

The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent mol­ecules (A and B). Each mol­ecule is build up from fused five- and six-membered rings with the former linked to a cyano­ethyl group. The indoline ring and two carbonyl O atoms of each mol­ecule are nearly copla...

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Detalles Bibliográficos
Autores principales: Qachchachi, Fatima-Zahrae, Kandri Rodi, Youssef, Essassi, El Mokhtar, Bodensteiner, Michael, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998493/
https://www.ncbi.nlm.nih.gov/pubmed/24765047
http://dx.doi.org/10.1107/S1600536814003985
Descripción
Sumario:The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent mol­ecules (A and B). Each mol­ecule is build up from fused five- and six-membered rings with the former linked to a cyano­ethyl group. The indoline ring and two carbonyl O atoms of each mol­ecule are nearly coplanar, with the largest deviations from the mean planes being 0.0198 (9) (mol­ecule A) and 0.0902 (9) Å (mol­ecule B), each by a carbonyl O atom. The fused ring system is nearly perpendicular to the mean plane passing through the cyano­ethyl chains, as indicated by the dihedral angles between them of 69.72 (9) (mol­ecule A) and 69.15 (9)° (mol­ecule B). In the crystal, mol­ecules are linked by C—H⋯O and π–π [inter­centroid distance between inversion-related indoline (A) rings = 3.6804 (7) Å] inter­actions into a double layer that stacks along the a-axis direction.