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3-(2,3-Dioxoindolin-1-yl)propane­nitrile

The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent mol­ecules (A and B). Each mol­ecule is build up from fused five- and six-membered rings with the former linked to a cyano­ethyl group. The indoline ring and two carbonyl O atoms of each mol­ecule are nearly copla...

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Autores principales: Qachchachi, Fatima-Zahrae, Kandri Rodi, Youssef, Essassi, El Mokhtar, Bodensteiner, Michael, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998493/
https://www.ncbi.nlm.nih.gov/pubmed/24765047
http://dx.doi.org/10.1107/S1600536814003985
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author Qachchachi, Fatima-Zahrae
Kandri Rodi, Youssef
Essassi, El Mokhtar
Bodensteiner, Michael
El Ammari, Lahcen
author_facet Qachchachi, Fatima-Zahrae
Kandri Rodi, Youssef
Essassi, El Mokhtar
Bodensteiner, Michael
El Ammari, Lahcen
author_sort Qachchachi, Fatima-Zahrae
collection PubMed
description The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent mol­ecules (A and B). Each mol­ecule is build up from fused five- and six-membered rings with the former linked to a cyano­ethyl group. The indoline ring and two carbonyl O atoms of each mol­ecule are nearly coplanar, with the largest deviations from the mean planes being 0.0198 (9) (mol­ecule A) and 0.0902 (9) Å (mol­ecule B), each by a carbonyl O atom. The fused ring system is nearly perpendicular to the mean plane passing through the cyano­ethyl chains, as indicated by the dihedral angles between them of 69.72 (9) (mol­ecule A) and 69.15 (9)° (mol­ecule B). In the crystal, mol­ecules are linked by C—H⋯O and π–π [inter­centroid distance between inversion-related indoline (A) rings = 3.6804 (7) Å] inter­actions into a double layer that stacks along the a-axis direction.
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spelling pubmed-39984932014-04-24 3-(2,3-Dioxoindolin-1-yl)propane­nitrile Qachchachi, Fatima-Zahrae Kandri Rodi, Youssef Essassi, El Mokhtar Bodensteiner, Michael El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent mol­ecules (A and B). Each mol­ecule is build up from fused five- and six-membered rings with the former linked to a cyano­ethyl group. The indoline ring and two carbonyl O atoms of each mol­ecule are nearly coplanar, with the largest deviations from the mean planes being 0.0198 (9) (mol­ecule A) and 0.0902 (9) Å (mol­ecule B), each by a carbonyl O atom. The fused ring system is nearly perpendicular to the mean plane passing through the cyano­ethyl chains, as indicated by the dihedral angles between them of 69.72 (9) (mol­ecule A) and 69.15 (9)° (mol­ecule B). In the crystal, mol­ecules are linked by C—H⋯O and π–π [inter­centroid distance between inversion-related indoline (A) rings = 3.6804 (7) Å] inter­actions into a double layer that stacks along the a-axis direction. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998493/ /pubmed/24765047 http://dx.doi.org/10.1107/S1600536814003985 Text en © Qachchachi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Qachchachi, Fatima-Zahrae
Kandri Rodi, Youssef
Essassi, El Mokhtar
Bodensteiner, Michael
El Ammari, Lahcen
3-(2,3-Dioxoindolin-1-yl)propane­nitrile
title 3-(2,3-Dioxoindolin-1-yl)propane­nitrile
title_full 3-(2,3-Dioxoindolin-1-yl)propane­nitrile
title_fullStr 3-(2,3-Dioxoindolin-1-yl)propane­nitrile
title_full_unstemmed 3-(2,3-Dioxoindolin-1-yl)propane­nitrile
title_short 3-(2,3-Dioxoindolin-1-yl)propane­nitrile
title_sort 3-(2,3-dioxoindolin-1-yl)propane­nitrile
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998493/
https://www.ncbi.nlm.nih.gov/pubmed/24765047
http://dx.doi.org/10.1107/S1600536814003985
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