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3-(2,3-Dioxoindolin-1-yl)propanenitrile
The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent molecules (A and B). Each molecule is build up from fused five- and six-membered rings with the former linked to a cyanoethyl group. The indoline ring and two carbonyl O atoms of each molecule are nearly copla...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998493/ https://www.ncbi.nlm.nih.gov/pubmed/24765047 http://dx.doi.org/10.1107/S1600536814003985 |
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author | Qachchachi, Fatima-Zahrae Kandri Rodi, Youssef Essassi, El Mokhtar Bodensteiner, Michael El Ammari, Lahcen |
author_facet | Qachchachi, Fatima-Zahrae Kandri Rodi, Youssef Essassi, El Mokhtar Bodensteiner, Michael El Ammari, Lahcen |
author_sort | Qachchachi, Fatima-Zahrae |
collection | PubMed |
description | The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent molecules (A and B). Each molecule is build up from fused five- and six-membered rings with the former linked to a cyanoethyl group. The indoline ring and two carbonyl O atoms of each molecule are nearly coplanar, with the largest deviations from the mean planes being 0.0198 (9) (molecule A) and 0.0902 (9) Å (molecule B), each by a carbonyl O atom. The fused ring system is nearly perpendicular to the mean plane passing through the cyanoethyl chains, as indicated by the dihedral angles between them of 69.72 (9) (molecule A) and 69.15 (9)° (molecule B). In the crystal, molecules are linked by C—H⋯O and π–π [intercentroid distance between inversion-related indoline (A) rings = 3.6804 (7) Å] interactions into a double layer that stacks along the a-axis direction. |
format | Online Article Text |
id | pubmed-3998493 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39984932014-04-24 3-(2,3-Dioxoindolin-1-yl)propanenitrile Qachchachi, Fatima-Zahrae Kandri Rodi, Youssef Essassi, El Mokhtar Bodensteiner, Michael El Ammari, Lahcen Acta Crystallogr Sect E Struct Rep Online Organic Papers The asymmetric unit of the title compound, C(11)H(8)N(2)O(2), contains two independent molecules (A and B). Each molecule is build up from fused five- and six-membered rings with the former linked to a cyanoethyl group. The indoline ring and two carbonyl O atoms of each molecule are nearly coplanar, with the largest deviations from the mean planes being 0.0198 (9) (molecule A) and 0.0902 (9) Å (molecule B), each by a carbonyl O atom. The fused ring system is nearly perpendicular to the mean plane passing through the cyanoethyl chains, as indicated by the dihedral angles between them of 69.72 (9) (molecule A) and 69.15 (9)° (molecule B). In the crystal, molecules are linked by C—H⋯O and π–π [intercentroid distance between inversion-related indoline (A) rings = 3.6804 (7) Å] interactions into a double layer that stacks along the a-axis direction. International Union of Crystallography 2014-02-26 /pmc/articles/PMC3998493/ /pubmed/24765047 http://dx.doi.org/10.1107/S1600536814003985 Text en © Qachchachi et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Qachchachi, Fatima-Zahrae Kandri Rodi, Youssef Essassi, El Mokhtar Bodensteiner, Michael El Ammari, Lahcen 3-(2,3-Dioxoindolin-1-yl)propanenitrile |
title | 3-(2,3-Dioxoindolin-1-yl)propanenitrile |
title_full | 3-(2,3-Dioxoindolin-1-yl)propanenitrile |
title_fullStr | 3-(2,3-Dioxoindolin-1-yl)propanenitrile |
title_full_unstemmed | 3-(2,3-Dioxoindolin-1-yl)propanenitrile |
title_short | 3-(2,3-Dioxoindolin-1-yl)propanenitrile |
title_sort | 3-(2,3-dioxoindolin-1-yl)propanenitrile |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998493/ https://www.ncbi.nlm.nih.gov/pubmed/24765047 http://dx.doi.org/10.1107/S1600536814003985 |
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