trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate

The title compound, [Pd(SC(6)H(4)F-p)Cl(PPh(3))(2)]·0.5CH(3)OH, features a Pd(II) complex with two tri­phenyl­phosphane (PPh(3)) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distort...

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Detalles Bibliográficos
Autores principales: Avila-Sorrosa, Alcives, Santacruz-Juárez, Ericka, Reyes-Arellano, Alicia, Reyes-Martínez, Reyna, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998499/
https://www.ncbi.nlm.nih.gov/pubmed/24764953
http://dx.doi.org/10.1107/S1600536814002499
Descripción
Sumario:The title compound, [Pd(SC(6)H(4)F-p)Cl(PPh(3))(2)]·0.5CH(3)OH, features a Pd(II) complex with two tri­phenyl­phosphane (PPh(3)) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd(II) ion. The methanol solvent mol­ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C—H⋯Cl hydrogen-bonding inter­actions between the complex mol­ecules generate chain frameworks parallel to [010].

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