trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate

The title compound, [Pd(SC(6)H(4)F-p)Cl(PPh(3))(2)]·0.5CH(3)OH, features a Pd(II) complex with two tri­phenyl­phosphane (PPh(3)) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distort...

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Autores principales: Avila-Sorrosa, Alcives, Santacruz-Juárez, Ericka, Reyes-Arellano, Alicia, Reyes-Martínez, Reyna, Morales-Morales, David
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998499/
https://www.ncbi.nlm.nih.gov/pubmed/24764953
http://dx.doi.org/10.1107/S1600536814002499
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author Avila-Sorrosa, Alcives
Santacruz-Juárez, Ericka
Reyes-Arellano, Alicia
Reyes-Martínez, Reyna
Morales-Morales, David
author_facet Avila-Sorrosa, Alcives
Santacruz-Juárez, Ericka
Reyes-Arellano, Alicia
Reyes-Martínez, Reyna
Morales-Morales, David
author_sort Avila-Sorrosa, Alcives
collection PubMed
description The title compound, [Pd(SC(6)H(4)F-p)Cl(PPh(3))(2)]·0.5CH(3)OH, features a Pd(II) complex with two tri­phenyl­phosphane (PPh(3)) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd(II) ion. The methanol solvent mol­ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C—H⋯Cl hydrogen-bonding inter­actions between the complex mol­ecules generate chain frameworks parallel to [010].
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spelling pubmed-39984992014-04-24 trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate Avila-Sorrosa, Alcives Santacruz-Juárez, Ericka Reyes-Arellano, Alicia Reyes-Martínez, Reyna Morales-Morales, David Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, [Pd(SC(6)H(4)F-p)Cl(PPh(3))(2)]·0.5CH(3)OH, features a Pd(II) complex with two tri­phenyl­phosphane (PPh(3)) ligands arranged in a trans conformation, with one chloride and one 4-fluoro­benzene­thiol­ate ligand completing the coordination sphere, giving rise to a slightly distorted square-planar geometry of the Pd(II) ion. The methanol solvent mol­ecule is disordered about an inversion centre with an occupancy of 0.25 for each molecule. In the crystal, weak C—H⋯Cl hydrogen-bonding inter­actions between the complex mol­ecules generate chain frameworks parallel to [010]. International Union of Crystallography 2014-02-12 /pmc/articles/PMC3998499/ /pubmed/24764953 http://dx.doi.org/10.1107/S1600536814002499 Text en © Avila-Sorrosa et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Avila-Sorrosa, Alcives
Santacruz-Juárez, Ericka
Reyes-Arellano, Alicia
Reyes-Martínez, Reyna
Morales-Morales, David
trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate
title trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate
title_full trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate
title_fullStr trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate
title_full_unstemmed trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate
title_short trans-Chlorido­(4-fluoro­benzene­thiol­ato-κS)bis­(tri­phenyl­phosphane-κP)palladium(II) methanol hemisolvate
title_sort trans-chlorido­(4-fluoro­benzene­thiol­ato-κs)bis­(tri­phenyl­phosphane-κp)palladium(ii) methanol hemisolvate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998499/
https://www.ncbi.nlm.nih.gov/pubmed/24764953
http://dx.doi.org/10.1107/S1600536814002499
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