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Poly[(μ(3)-3,5-dinitrobenzoato-κ(3) O (1):O (1′):O (3))(μ(2)-hydroxido-κ(2) O:O)copper(II)]
The title complex, [Cu{μ(3)-O(2)CC(6)H(3)(NO(2))(2)-3,5}(μ-OH)](n), features zigzag chains in which successive pairs of Cu(II) atoms are connected by OH bridges and bidentate carboxylate ligands, leading to six-membered Cu(O)(OCO)Cu rings. The zigzag chains are connected into a three-dimensional ar...
| Autores principales: | , , , , , |
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| Formato: | Online Artículo Texto |
| Lenguaje: | English |
| Publicado: |
International Union of Crystallography
2014
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| Materias: | |
| Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998500/ https://www.ncbi.nlm.nih.gov/pubmed/24764942 http://dx.doi.org/10.1107/S1600536814004280 |
| _version_ | 1782313375716343808 |
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| author | Sinha, B. Dey, G. C. Sarkar, B. Roy, A. Ng, Seik Weng Tiekink, Edward R. T. |
| author_facet | Sinha, B. Dey, G. C. Sarkar, B. Roy, A. Ng, Seik Weng Tiekink, Edward R. T. |
| author_sort | Sinha, B. |
| collection | PubMed |
| description | The title complex, [Cu{μ(3)-O(2)CC(6)H(3)(NO(2))(2)-3,5}(μ-OH)](n), features zigzag chains in which successive pairs of Cu(II) atoms are connected by OH bridges and bidentate carboxylate ligands, leading to six-membered Cu(O)(OCO)Cu rings. The zigzag chains are connected into a three-dimensional architecture by Cu—O(nitro) bonds. The coordination geometry of the Cu(II) atom is square-pyramidal, with the axial position occupied by the nitro O atom, which forms the longer Cu—O bond. Bifurcated hydroxy–nitro O—H⋯O hydrogen bonds contribute to the stability of the crystal structure. |
| format | Online Article Text |
| id | pubmed-3998500 |
| institution | National Center for Biotechnology Information |
| language | English |
| publishDate | 2014 |
| publisher | International Union of Crystallography |
| record_format | MEDLINE/PubMed |
| spelling | pubmed-39985002014-04-24 Poly[(μ(3)-3,5-dinitrobenzoato-κ(3) O (1):O (1′):O (3))(μ(2)-hydroxido-κ(2) O:O)copper(II)] Sinha, B. Dey, G. C. Sarkar, B. Roy, A. Ng, Seik Weng Tiekink, Edward R. T. Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title complex, [Cu{μ(3)-O(2)CC(6)H(3)(NO(2))(2)-3,5}(μ-OH)](n), features zigzag chains in which successive pairs of Cu(II) atoms are connected by OH bridges and bidentate carboxylate ligands, leading to six-membered Cu(O)(OCO)Cu rings. The zigzag chains are connected into a three-dimensional architecture by Cu—O(nitro) bonds. The coordination geometry of the Cu(II) atom is square-pyramidal, with the axial position occupied by the nitro O atom, which forms the longer Cu—O bond. Bifurcated hydroxy–nitro O—H⋯O hydrogen bonds contribute to the stability of the crystal structure. International Union of Crystallography 2014-02-28 /pmc/articles/PMC3998500/ /pubmed/24764942 http://dx.doi.org/10.1107/S1600536814004280 Text en © Sinha et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
| spellingShingle | Metal-Organic Papers Sinha, B. Dey, G. C. Sarkar, B. Roy, A. Ng, Seik Weng Tiekink, Edward R. T. Poly[(μ(3)-3,5-dinitrobenzoato-κ(3) O (1):O (1′):O (3))(μ(2)-hydroxido-κ(2) O:O)copper(II)] |
| title | Poly[(μ(3)-3,5-dinitrobenzoato-κ(3)
O
(1):O
(1′):O
(3))(μ(2)-hydroxido-κ(2)
O:O)copper(II)] |
| title_full | Poly[(μ(3)-3,5-dinitrobenzoato-κ(3)
O
(1):O
(1′):O
(3))(μ(2)-hydroxido-κ(2)
O:O)copper(II)] |
| title_fullStr | Poly[(μ(3)-3,5-dinitrobenzoato-κ(3)
O
(1):O
(1′):O
(3))(μ(2)-hydroxido-κ(2)
O:O)copper(II)] |
| title_full_unstemmed | Poly[(μ(3)-3,5-dinitrobenzoato-κ(3)
O
(1):O
(1′):O
(3))(μ(2)-hydroxido-κ(2)
O:O)copper(II)] |
| title_short | Poly[(μ(3)-3,5-dinitrobenzoato-κ(3)
O
(1):O
(1′):O
(3))(μ(2)-hydroxido-κ(2)
O:O)copper(II)] |
| title_sort | poly[(μ(3)-3,5-dinitrobenzoato-κ(3)
o
(1):o
(1′):o
(3))(μ(2)-hydroxido-κ(2)
o:o)copper(ii)] |
| topic | Metal-Organic Papers |
| url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998500/ https://www.ncbi.nlm.nih.gov/pubmed/24764942 http://dx.doi.org/10.1107/S1600536814004280 |
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