4-Bromo-N-(2-nitro­phen­yl)benzamide

The title nitro­phenyl benzamide, C(13)H(9)BrN(2)O(3), with two mol­ecules in the asymmetric unit, has dihedral angles of 16.78 (15) and 18.87 (14)° between the benzene rings. An intra­molecular N—H⋯O hydrogen bond is observed in each mol­ecule. In the crystal, the molecules are linked by weak C—H⋯O...

Descripción completa

Detalles Bibliográficos
Autores principales: Moreno-Fuquen, Rodolfo, Azcárate, Alexis, Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998505/
https://www.ncbi.nlm.nih.gov/pubmed/24765035
http://dx.doi.org/10.1107/S1600536814003298
Descripción
Sumario:The title nitro­phenyl benzamide, C(13)H(9)BrN(2)O(3), with two mol­ecules in the asymmetric unit, has dihedral angles of 16.78 (15) and 18.87 (14)° between the benzene rings. An intra­molecular N—H⋯O hydrogen bond is observed in each mol­ecule. In the crystal, the molecules are linked by weak C—H⋯O inter­actions; halogen–halogen inter­actions are also observed [Br⋯Br = 3.4976 (7) Å]. These inter­actions form R (2) (2)(10), R (2) (2)(15) and R (6) (6)(32) edge-fused rings along [010].

Ejemplares similares