4-Bromo-N-(2-nitro­phen­yl)benzamide

The title nitro­phenyl benzamide, C(13)H(9)BrN(2)O(3), with two mol­ecules in the asymmetric unit, has dihedral angles of 16.78 (15) and 18.87 (14)° between the benzene rings. An intra­molecular N—H⋯O hydrogen bond is observed in each mol­ecule. In the crystal, the molecules are linked by weak C—H⋯O...

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Autores principales: Moreno-Fuquen, Rodolfo, Azcárate, Alexis, Kennedy, Alan R.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998505/
https://www.ncbi.nlm.nih.gov/pubmed/24765035
http://dx.doi.org/10.1107/S1600536814003298
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author Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
author_facet Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
author_sort Moreno-Fuquen, Rodolfo
collection PubMed
description The title nitro­phenyl benzamide, C(13)H(9)BrN(2)O(3), with two mol­ecules in the asymmetric unit, has dihedral angles of 16.78 (15) and 18.87 (14)° between the benzene rings. An intra­molecular N—H⋯O hydrogen bond is observed in each mol­ecule. In the crystal, the molecules are linked by weak C—H⋯O inter­actions; halogen–halogen inter­actions are also observed [Br⋯Br = 3.4976 (7) Å]. These inter­actions form R (2) (2)(10), R (2) (2)(15) and R (6) (6)(32) edge-fused rings along [010].
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spelling pubmed-39985052014-04-24 4-Bromo-N-(2-nitro­phen­yl)benzamide Moreno-Fuquen, Rodolfo Azcárate, Alexis Kennedy, Alan R. Acta Crystallogr Sect E Struct Rep Online Organic Papers The title nitro­phenyl benzamide, C(13)H(9)BrN(2)O(3), with two mol­ecules in the asymmetric unit, has dihedral angles of 16.78 (15) and 18.87 (14)° between the benzene rings. An intra­molecular N—H⋯O hydrogen bond is observed in each mol­ecule. In the crystal, the molecules are linked by weak C—H⋯O inter­actions; halogen–halogen inter­actions are also observed [Br⋯Br = 3.4976 (7) Å]. These inter­actions form R (2) (2)(10), R (2) (2)(15) and R (6) (6)(32) edge-fused rings along [010]. International Union of Crystallography 2014-02-22 /pmc/articles/PMC3998505/ /pubmed/24765035 http://dx.doi.org/10.1107/S1600536814003298 Text en © Moreno-Fuquen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Moreno-Fuquen, Rodolfo
Azcárate, Alexis
Kennedy, Alan R.
4-Bromo-N-(2-nitro­phen­yl)benzamide
title 4-Bromo-N-(2-nitro­phen­yl)benzamide
title_full 4-Bromo-N-(2-nitro­phen­yl)benzamide
title_fullStr 4-Bromo-N-(2-nitro­phen­yl)benzamide
title_full_unstemmed 4-Bromo-N-(2-nitro­phen­yl)benzamide
title_short 4-Bromo-N-(2-nitro­phen­yl)benzamide
title_sort 4-bromo-n-(2-nitro­phen­yl)benzamide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998505/
https://www.ncbi.nlm.nih.gov/pubmed/24765035
http://dx.doi.org/10.1107/S1600536814003298
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AT azcaratealexis 4bromon2nitrophenylbenzamide
AT kennedyalanr 4bromon2nitrophenylbenzamide

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