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1-(Prop-2-yn­yl)indoline-2,3-dione

The structure of the title compound, C(11)H(7)NO(2), is isotypic to that of its homologue, 1-octylindoline-2,3-dione [Qachchachi et al. (2013 ▶). Acta Cryst. E69, o1801]. The indoline ring and the two carbonyl O atoms are approximately coplanar, the largest deviation from the mean plane being 0.021 ...

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Detalles Bibliográficos
Autores principales: Qachchachi, Fatima-Zahrae, Ouazzani Chahdi, Fouad, Misbahi, Houria, Bodensteiner, Michael, El Ammari, Lahcen
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998508/
https://www.ncbi.nlm.nih.gov/pubmed/24765046
http://dx.doi.org/10.1107/S1600536814003973
Descripción
Sumario:The structure of the title compound, C(11)H(7)NO(2), is isotypic to that of its homologue, 1-octylindoline-2,3-dione [Qachchachi et al. (2013 ▶). Acta Cryst. E69, o1801]. The indoline ring and the two carbonyl O atoms are approximately coplanar, the largest deviation from the mean plane being 0.021 (1) Å for one of the O atoms. The mean plane through the fused ring system is nearly perpendicular to the propynyl group, as indicated by the N—C—C—C torsion angle of 77.9 (1)°. In the crystal, mol­ecules are linked by C—H⋯O hydrogen bonds and π–π inter­actions between benzene rings [inter­centroid distance = 3.5630 (10) Å], forming a three-dimensional structure.