6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide

In the title compound, C(15)H(10)Cl(2)N(2)O, the dihedral angle between the mean planes of the phenyl ring and the 10-membered quinazoline ring is 63.3 (4)°. In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(10) graph-set ring motifs...

Descripción completa

Detalles Bibliográficos
Autores principales: Yamuna, Thammarse S., Jasinski, Jerry P., Kaur, Manpreet, Yathirajan, Hemmige S., Siddegowda, Maravanahalli S.
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998526/
https://www.ncbi.nlm.nih.gov/pubmed/24826145
http://dx.doi.org/10.1107/S1600536814005303
_version_ 1782313380039622656
author Yamuna, Thammarse S.
Jasinski, Jerry P.
Kaur, Manpreet
Yathirajan, Hemmige S.
Siddegowda, Maravanahalli S.
author_facet Yamuna, Thammarse S.
Jasinski, Jerry P.
Kaur, Manpreet
Yathirajan, Hemmige S.
Siddegowda, Maravanahalli S.
author_sort Yamuna, Thammarse S.
collection PubMed
description In the title compound, C(15)H(10)Cl(2)N(2)O, the dihedral angle between the mean planes of the phenyl ring and the 10-membered quinazoline ring is 63.3 (4)°. In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(10) graph-set ring motifs. In addition, weak π–π stacking inter­actions [minimum centroid–centroid separation = 3.6810 (8) Å] are observed, which contribute to the formation of a supramolecular assembly in the packing array.
format Online
Article
Text
id pubmed-3998526
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39985262014-05-13 6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide Yamuna, Thammarse S. Jasinski, Jerry P. Kaur, Manpreet Yathirajan, Hemmige S. Siddegowda, Maravanahalli S. Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(15)H(10)Cl(2)N(2)O, the dihedral angle between the mean planes of the phenyl ring and the 10-membered quinazoline ring is 63.3 (4)°. In the crystal, pairs of weak C—H⋯O inter­actions link the mol­ecules into centrosymmetric dimers, forming R (2) (2)(10) graph-set ring motifs. In addition, weak π–π stacking inter­actions [minimum centroid–centroid separation = 3.6810 (8) Å] are observed, which contribute to the formation of a supramolecular assembly in the packing array. International Union of Crystallography 2014-03-15 /pmc/articles/PMC3998526/ /pubmed/24826145 http://dx.doi.org/10.1107/S1600536814005303 Text en © Yamuna et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Yamuna, Thammarse S.
Jasinski, Jerry P.
Kaur, Manpreet
Yathirajan, Hemmige S.
Siddegowda, Maravanahalli S.
6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
title 6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
title_full 6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
title_fullStr 6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
title_full_unstemmed 6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
title_short 6-Chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
title_sort 6-chloro-2-chloro­methyl-4-phenyl­quinazoline 3-oxide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998526/
https://www.ncbi.nlm.nih.gov/pubmed/24826145
http://dx.doi.org/10.1107/S1600536814005303
work_keys_str_mv AT yamunathammarses 6chloro2chloromethyl4phenylquinazoline3oxide
AT jasinskijerryp 6chloro2chloromethyl4phenylquinazoline3oxide
AT kaurmanpreet 6chloro2chloromethyl4phenylquinazoline3oxide
AT yathirajanhemmiges 6chloro2chloromethyl4phenylquinazoline3oxide
AT siddegowdamaravanahallis 6chloro2chloromethyl4phenylquinazoline3oxide

Ejemplares similares