N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine

In the title compound, C(17)H(21)N(3)O, the C—N bond lengths in the guanidine unit are 1.2889 (19), 1.3682 (19) and 1.408 (2) Å, indicating double- and single-bond character. The N—C—N angles are 115.10 (13), 119.29 (15) and 125.61 (14)°, showing a deviation of the CN(3) plane from an ideal trigonal...

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Frey, Wolfgang, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998528/
https://www.ncbi.nlm.nih.gov/pubmed/24826159
http://dx.doi.org/10.1107/S1600536814005819
Descripción
Sumario:In the title compound, C(17)H(21)N(3)O, the C—N bond lengths in the guanidine unit are 1.2889 (19), 1.3682 (19) and 1.408 (2) Å, indicating double- and single-bond character. The N—C—N angles are 115.10 (13), 119.29 (15) and 125.61 (14)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. In the crystal, non-classical C—H⋯O hydrogen bonds between methyl H atoms and meth­oxy O atoms are present, generating centrosymmetric dimers running in the [101] direction.

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