N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine

In the title compound, C(17)H(21)N(3)O, the C—N bond lengths in the guanidine unit are 1.2889 (19), 1.3682 (19) and 1.408 (2) Å, indicating double- and single-bond character. The N—C—N angles are 115.10 (13), 119.29 (15) and 125.61 (14)°, showing a deviation of the CN(3) plane from an ideal trigonal...

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Detalles Bibliográficos
Autores principales: Tiritiris, Ioannis, Frey, Wolfgang, Kantlehner, Willi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998528/
https://www.ncbi.nlm.nih.gov/pubmed/24826159
http://dx.doi.org/10.1107/S1600536814005819
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author Tiritiris, Ioannis
Frey, Wolfgang
Kantlehner, Willi
author_facet Tiritiris, Ioannis
Frey, Wolfgang
Kantlehner, Willi
author_sort Tiritiris, Ioannis
collection PubMed
description In the title compound, C(17)H(21)N(3)O, the C—N bond lengths in the guanidine unit are 1.2889 (19), 1.3682 (19) and 1.408 (2) Å, indicating double- and single-bond character. The N—C—N angles are 115.10 (13), 119.29 (15) and 125.61 (14)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. In the crystal, non-classical C—H⋯O hydrogen bonds between methyl H atoms and meth­oxy O atoms are present, generating centrosymmetric dimers running in the [101] direction.
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spelling pubmed-39985282014-05-13 N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine Tiritiris, Ioannis Frey, Wolfgang Kantlehner, Willi Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title compound, C(17)H(21)N(3)O, the C—N bond lengths in the guanidine unit are 1.2889 (19), 1.3682 (19) and 1.408 (2) Å, indicating double- and single-bond character. The N—C—N angles are 115.10 (13), 119.29 (15) and 125.61 (14)°, showing a deviation of the CN(3) plane from an ideal trigonal–planar geometry. In the crystal, non-classical C—H⋯O hydrogen bonds between methyl H atoms and meth­oxy O atoms are present, generating centrosymmetric dimers running in the [101] direction. International Union of Crystallography 2014-03-22 /pmc/articles/PMC3998528/ /pubmed/24826159 http://dx.doi.org/10.1107/S1600536814005819 Text en © Tiritiris et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Tiritiris, Ioannis
Frey, Wolfgang
Kantlehner, Willi
N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine
title N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine
title_full N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine
title_fullStr N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine
title_full_unstemmed N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine
title_short N′′-(4-Meth­oxy­phen­yl)-N,N,N′-trimethyl-N′-phenyl­guanidine
title_sort n′′-(4-meth­oxy­phen­yl)-n,n,n′-trimethyl-n′-phenyl­guanidine
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998528/
https://www.ncbi.nlm.nih.gov/pubmed/24826159
http://dx.doi.org/10.1107/S1600536814005819
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