2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane

The title compound, C(30)H(28)N(2), is a product of the condensation reaction of 2-methyl-4-phenyl­aniline and butane-2,3-dione. The mol­ecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methyl­ph...

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Autores principales: Chen, Jingjing, Yuan, Jianchao, Zhao, Jie, Xu, Weibing, Mu, Yanqiong
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998529/
https://www.ncbi.nlm.nih.gov/pubmed/24826155
http://dx.doi.org/10.1107/S1600536814005686
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author Chen, Jingjing
Yuan, Jianchao
Zhao, Jie
Xu, Weibing
Mu, Yanqiong
author_facet Chen, Jingjing
Yuan, Jianchao
Zhao, Jie
Xu, Weibing
Mu, Yanqiong
author_sort Chen, Jingjing
collection PubMed
description The title compound, C(30)H(28)N(2), is a product of the condensation reaction of 2-methyl-4-phenyl­aniline and butane-2,3-dione. The mol­ecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methyl­phenyl group is 29.19 (76)°. The 1,4-di­aza­butadiene plane makes an angle of 70.1 (10)° with the N-bonded methyl­phenyl ring and an angle of 81.08 (97)° with the terminal phenyl group.
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spelling pubmed-39985292014-05-13 2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane Chen, Jingjing Yuan, Jianchao Zhao, Jie Xu, Weibing Mu, Yanqiong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(28)N(2), is a product of the condensation reaction of 2-methyl-4-phenyl­aniline and butane-2,3-dione. The mol­ecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methyl­phenyl group is 29.19 (76)°. The 1,4-di­aza­butadiene plane makes an angle of 70.1 (10)° with the N-bonded methyl­phenyl ring and an angle of 81.08 (97)° with the terminal phenyl group. International Union of Crystallography 2014-03-19 /pmc/articles/PMC3998529/ /pubmed/24826155 http://dx.doi.org/10.1107/S1600536814005686 Text en © Chen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Chen, Jingjing
Yuan, Jianchao
Zhao, Jie
Xu, Weibing
Mu, Yanqiong
2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane
title 2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane
title_full 2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane
title_fullStr 2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane
title_full_unstemmed 2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane
title_short 2,3-Bis[(3-methyl­biphenyl-4-yl)imino]­butane
title_sort 2,3-bis[(3-methyl­biphenyl-4-yl)imino]­butane
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998529/
https://www.ncbi.nlm.nih.gov/pubmed/24826155
http://dx.doi.org/10.1107/S1600536814005686
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AT zhaojie 23bis3methylbiphenyl4yliminobutane
AT xuweibing 23bis3methylbiphenyl4yliminobutane
AT muyanqiong 23bis3methylbiphenyl4yliminobutane

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