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2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane
The title compound, C(30)H(28)N(2), is a product of the condensation reaction of 2-methyl-4-phenylaniline and butane-2,3-dione. The molecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methylph...
Autores principales: | , , , , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998529/ https://www.ncbi.nlm.nih.gov/pubmed/24826155 http://dx.doi.org/10.1107/S1600536814005686 |
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author | Chen, Jingjing Yuan, Jianchao Zhao, Jie Xu, Weibing Mu, Yanqiong |
author_facet | Chen, Jingjing Yuan, Jianchao Zhao, Jie Xu, Weibing Mu, Yanqiong |
author_sort | Chen, Jingjing |
collection | PubMed |
description | The title compound, C(30)H(28)N(2), is a product of the condensation reaction of 2-methyl-4-phenylaniline and butane-2,3-dione. The molecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methylphenyl group is 29.19 (76)°. The 1,4-diazabutadiene plane makes an angle of 70.1 (10)° with the N-bonded methylphenyl ring and an angle of 81.08 (97)° with the terminal phenyl group. |
format | Online Article Text |
id | pubmed-3998529 |
institution | National Center for Biotechnology Information |
language | English |
publishDate | 2014 |
publisher | International Union of Crystallography |
record_format | MEDLINE/PubMed |
spelling | pubmed-39985292014-05-13 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane Chen, Jingjing Yuan, Jianchao Zhao, Jie Xu, Weibing Mu, Yanqiong Acta Crystallogr Sect E Struct Rep Online Organic Papers The title compound, C(30)H(28)N(2), is a product of the condensation reaction of 2-methyl-4-phenylaniline and butane-2,3-dione. The molecule lies on a crystallographic inversion centre. The C=N bond has an E conformation. The dihedral angle between the two benzene rings of the 4-phenyl-2-methylphenyl group is 29.19 (76)°. The 1,4-diazabutadiene plane makes an angle of 70.1 (10)° with the N-bonded methylphenyl ring and an angle of 81.08 (97)° with the terminal phenyl group. International Union of Crystallography 2014-03-19 /pmc/articles/PMC3998529/ /pubmed/24826155 http://dx.doi.org/10.1107/S1600536814005686 Text en © Chen et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited. |
spellingShingle | Organic Papers Chen, Jingjing Yuan, Jianchao Zhao, Jie Xu, Weibing Mu, Yanqiong 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane |
title | 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane |
title_full | 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane |
title_fullStr | 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane |
title_full_unstemmed | 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane |
title_short | 2,3-Bis[(3-methylbiphenyl-4-yl)imino]butane |
title_sort | 2,3-bis[(3-methylbiphenyl-4-yl)imino]butane |
topic | Organic Papers |
url | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998529/ https://www.ncbi.nlm.nih.gov/pubmed/24826155 http://dx.doi.org/10.1107/S1600536814005686 |
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