Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate

The title compound, (C(8)H(12)NO)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, crystallizes isotypically with its Mn(II) analogue. It consists of alternating layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co...

Descripción completa

Detalles Bibliográficos
Autores principales: Elboulali, Adel, Selmi, Ahmed, Ratel-Ramond, Nicolas, Rzaigui, Mohamed, Akriche, Samah Toumi
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Metal-Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998531/
https://www.ncbi.nlm.nih.gov/pubmed/24826105
http://dx.doi.org/10.1107/S1600536814006102
_version_ 1782313381132238848
author Elboulali, Adel
Selmi, Ahmed
Ratel-Ramond, Nicolas
Rzaigui, Mohamed
Akriche, Samah Toumi
author_facet Elboulali, Adel
Selmi, Ahmed
Ratel-Ramond, Nicolas
Rzaigui, Mohamed
Akriche, Samah Toumi
author_sort Elboulali, Adel
collection PubMed
description The title compound, (C(8)H(12)NO)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, crystallizes isotypically with its Mn(II) analogue. It consists of alternating layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co(2+) atom has an octa­hedral coordination sphere, defined by two water mol­ecules in apical positions and two H(2)P(2)O(7) (2−) ligands in equatorial positions. The cohesion between inorganic and organic layers is accomplished by a set of O—H⋯O and N—H⋯O hydrogen bonds involving the organic cation, the inorganic anion and the remaining lattice water mol­ecules.
format Online
Article
Text
id pubmed-3998531
institution National Center for Biotechnology Information
language English
publishDate 2014
publisher International Union of Crystallography
record_format MEDLINE/PubMed
spelling pubmed-39985312014-05-13 Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate Elboulali, Adel Selmi, Ahmed Ratel-Ramond, Nicolas Rzaigui, Mohamed Akriche, Samah Toumi Acta Crystallogr Sect E Struct Rep Online Metal-Organic Papers The title compound, (C(8)H(12)NO)(2)[Co(H(2)P(2)O(7))(2)(H(2)O)(2)]·2H(2)O, crystallizes isotypically with its Mn(II) analogue. It consists of alternating layers of organic cations and inorganic complex anions, extending parallel to (100). The complex cobaltate(II) anion exhibits -1 symmetry. Its Co(2+) atom has an octa­hedral coordination sphere, defined by two water mol­ecules in apical positions and two H(2)P(2)O(7) (2−) ligands in equatorial positions. The cohesion between inorganic and organic layers is accomplished by a set of O—H⋯O and N—H⋯O hydrogen bonds involving the organic cation, the inorganic anion and the remaining lattice water mol­ecules. International Union of Crystallography 2014-03-26 /pmc/articles/PMC3998531/ /pubmed/24826105 http://dx.doi.org/10.1107/S1600536814006102 Text en © Elboulali et al. 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Metal-Organic Papers
Elboulali, Adel
Selmi, Ahmed
Ratel-Ramond, Nicolas
Rzaigui, Mohamed
Akriche, Samah Toumi
Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate
title Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate
title_full Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate
title_fullStr Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate
title_full_unstemmed Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate
title_short Bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) O,O′)cobaltate(II) dihydrate
title_sort bis(2-meth­oxy­benzyl­ammonium) di­aqua­bis­(di­hydrogen diphosphato-κ(2) o,o′)cobaltate(ii) dihydrate
topic Metal-Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998531/
https://www.ncbi.nlm.nih.gov/pubmed/24826105
http://dx.doi.org/10.1107/S1600536814006102
work_keys_str_mv AT elboulaliadel bis2methoxybenzylammoniumdiaquabisdihydrogendiphosphatok2oocobaltateiidihydrate
AT selmiahmed bis2methoxybenzylammoniumdiaquabisdihydrogendiphosphatok2oocobaltateiidihydrate
AT ratelramondnicolas bis2methoxybenzylammoniumdiaquabisdihydrogendiphosphatok2oocobaltateiidihydrate
AT rzaiguimohamed bis2methoxybenzylammoniumdiaquabisdihydrogendiphosphatok2oocobaltateiidihydrate
AT akrichesamahtoumi bis2methoxybenzylammoniumdiaquabisdihydrogendiphosphatok2oocobaltateiidihydrate

Ejemplares similares