Dimethyl 3,3′-di­meth­oxy­biphenyl-4,4′-di­carboxyl­ate

In the title compound, C(18)H(18)O(6), the biphenyl moiety is twisted with a dihedral angle of 29.11 (10)°. The carbometh­oxy groups form C—C—C—O torsion angles of −18.3 (3) and −27.7 (3)° with the attached rings, as a result of steric hindrances from the nearby meth­oxy groups. In the absence of st...

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Detalles Bibliográficos
Autores principales: Lundvall, Fredrik, Wragg, David Stephen, Dietzel, Pascal D. C., Fjellvåg, Helmer
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Organic Papers
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998533/
https://www.ncbi.nlm.nih.gov/pubmed/24826151
http://dx.doi.org/10.1107/S1600536814005613
Descripción
Sumario:In the title compound, C(18)H(18)O(6), the biphenyl moiety is twisted with a dihedral angle of 29.11 (10)°. The carbometh­oxy groups form C—C—C—O torsion angles of −18.3 (3) and −27.7 (3)° with the attached rings, as a result of steric hindrances from the nearby meth­oxy groups. In the absence of stacking inter­actions and with no H⋯O contacts shorter than 2.7 Å, the packing is dominated by weaker van der Waals inter­actions.

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