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Diaquabis[5-(pyrazin-2-yl-κN (1))-3-(pyridin-3-yl)-1,2,4-triazolido-κN (1)]zinc
In the title compound, [Zn(C(11)H(7)N(6))(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion center, is N,N′-chelated by two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazolide anions and is further coordinated by two water molecules in a distorted N(4)O(2) octahedral geometry. In the anioni...
Autores principales: | , |
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Formato: | Online Artículo Texto |
Lenguaje: | English |
Publicado: |
International Union of Crystallography
2014
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Materias: | |
Acceso en línea: | https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998535/ https://www.ncbi.nlm.nih.gov/pubmed/24826085 http://dx.doi.org/10.1107/S1600536814004176 |
Sumario: | In the title compound, [Zn(C(11)H(7)N(6))(2)(H(2)O)(2)], the Zn(II) cation, located on an inversion center, is N,N′-chelated by two 5-(pyrazin-2-yl)-3-(pyridin-3-yl)-1,2,4-triazolide anions and is further coordinated by two water molecules in a distorted N(4)O(2) octahedral geometry. In the anionic ligand, the pyrazine and pyridine rings are twisted with respect to the central triazole ring by 5.77 (10) and 11.54 (10)°, respectively. In the crystal, classical O—H⋯N and weak C—H⋯O hydrogen bonds and π–π stacking interactions between aromatic rings [the centroid–centroid distances between triazole and pyrazine rings, and between triazole and pyridine rings are 3.623 (2) and 3.852 (2) Å, respectively] connect the molecules into a three-dimensional supramolecular architecture. |
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