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(E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide

In the title chromone-tethered benzohydrazide derivative, C(20)H(18)N(2)O(6), the atoms of the E-3-(hydrazonometh­yl)-4H-chromen-4-one segment are essentially coplanar, the largest deviation being 0.065 (6) Å. The dihedral angle between this segment and the benzene ring of the tri­meth­oxy­benzene u...

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Detalles Bibliográficos
Autores principales: Ishikawa, Yoshinobu, Watanabe, Kohzoh
Formato: Online Artículo Texto
Lenguaje:English
Publicado: International Union of Crystallography 2014
Materias:
Acceso en línea:https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998542/
https://www.ncbi.nlm.nih.gov/pubmed/24826169
http://dx.doi.org/10.1107/S1600536814005753
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author Ishikawa, Yoshinobu
Watanabe, Kohzoh
author_facet Ishikawa, Yoshinobu
Watanabe, Kohzoh
author_sort Ishikawa, Yoshinobu
collection PubMed
description In the title chromone-tethered benzohydrazide derivative, C(20)H(18)N(2)O(6), the atoms of the E-3-(hydrazonometh­yl)-4H-chromen-4-one segment are essentially coplanar, the largest deviation being 0.065 (6) Å. The dihedral angle between this segment and the benzene ring of the tri­meth­oxy­benzene unit is 40.18 (10) Å. In the crystal, the mol­ecule is linked to its inverse-symmetry equivalent by pairs of N—H⋯O hydrogen bonds and C—H⋯π inter­actions. The –CH=N—NH– segment is stacked on the benzene ring of the chromone unit of a translation-related equivalent mol­ecule [centroid–centroid distance = 3.413 (6) Å].
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spelling pubmed-39985422014-05-13 (E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide Ishikawa, Yoshinobu Watanabe, Kohzoh Acta Crystallogr Sect E Struct Rep Online Organic Papers In the title chromone-tethered benzohydrazide derivative, C(20)H(18)N(2)O(6), the atoms of the E-3-(hydrazonometh­yl)-4H-chromen-4-one segment are essentially coplanar, the largest deviation being 0.065 (6) Å. The dihedral angle between this segment and the benzene ring of the tri­meth­oxy­benzene unit is 40.18 (10) Å. In the crystal, the mol­ecule is linked to its inverse-symmetry equivalent by pairs of N—H⋯O hydrogen bonds and C—H⋯π inter­actions. The –CH=N—NH– segment is stacked on the benzene ring of the chromone unit of a translation-related equivalent mol­ecule [centroid–centroid distance = 3.413 (6) Å]. International Union of Crystallography 2014-03-26 /pmc/articles/PMC3998542/ /pubmed/24826169 http://dx.doi.org/10.1107/S1600536814005753 Text en © Ishikawa and Watanabe 2014 http://creativecommons.org/licenses/by/2.0/uk/ This is an open-access article distributed under the terms of the Creative Commons Attribution Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited.
spellingShingle Organic Papers
Ishikawa, Yoshinobu
Watanabe, Kohzoh
(E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide
title (E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide
title_full (E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide
title_fullStr (E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide
title_full_unstemmed (E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide
title_short (E)-3,4,5-Trimeth­oxy-N′-[(4-oxo-4H-chromen-3-yl)methyl­idene]benzo­hydrazide
title_sort (e)-3,4,5-trimeth­oxy-n′-[(4-oxo-4h-chromen-3-yl)methyl­idene]benzo­hydrazide
topic Organic Papers
url https://www.ncbi.nlm.nih.gov/pmc/articles/PMC3998542/
https://www.ncbi.nlm.nih.gov/pubmed/24826169
http://dx.doi.org/10.1107/S1600536814005753
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